Answer:
Kb = 1.77x10⁻⁵
Explanation:
When NH₃, a weak base, is in equilibrium with waterm the reaction that occurs is:
NH₃(aq) + H₂O(l) ⇄ NH₄⁺(aq) + OH⁻(aq)
And the dissociation constant, Kb, for this equilibrium is:
Kb = [NH₄⁺] [OH⁻] / [NH₃]
To find Kb you need to find the concentration of each species. The equilibrium concentrations are:
[NH₃] = 0.950M - X
[NH₄⁺] = X
[OH⁻] = X
<em>Where X is reaction coordinate.</em>
You can know [OH⁻] and, therefore, X, with pH of the solution, thus:
pH = -log [H⁺] = 11.612
[H⁺] = 2.4434x10⁻¹²
As 1x10⁻¹⁴ = [H⁺] [OH⁻]
1x10⁻¹⁴ / 2.4434x10⁻¹² = [OH⁻]
4.0926x10⁻³ = [OH⁻] = X
Replacing, concentrations of the species are:
[NH₃] = 0.950M - X
[NH₄⁺] = X
[OH⁻] = X
[NH₃] = 0.9459M
[NH₄⁺] = 4.0926x10⁻³M
[OH⁻] = 4.0926x10⁻³M
Replacing in Kb expression:
Kb = [NH₄⁺] [OH⁻] / [NH₃]
Kb = [4.0926x10⁻³M] [4.0926x10⁻³M] / [0.9459M]
<h3>Kb = 1.77x10⁻⁵</h3>
47% yield.
First, let's determine how many moles of ethane was used and how many moles of CO2 produced. Start with the respective atomic weights.
Atomic weight carbon = 12.0107
Atomic weight hydrogen = 1.00794
Atomic weight oxygen = 15.999
Molar mass C2H6 = 2 * 12.0107 + 6 * 1.00794 = 30.06904 g/mol
Molar mass CO2 = 12.0107 + 2 * 15.999 = 44.0087 g/mol
Moles C2H6 = 8 g / 30.06904 g/mol = 0.266054387 mol
Moles CO2 = 11 g / 44.0087 g/mol = 0.249950578 mol
Looking at the balanced equation, for every 2 moles of C2H6 consumed, 4 moles of CO2 should be produced. So at 100% yield, we should have 0.266054387 / 2 * 4 = 0.532108774 moles of CO2. But we only have 0.249950578 moles, or 0.249950578 / 0.532108774 = 0.46973587 =
46.973587% of what was expected.
Rounding to 2 significant figures gives 47% yield.
It depends on what the material is.
The total mass is the sum of the masses.
It is
5543 + 23.45 + 697.4 mg = 6263.85 mg
Answer: 6263.85 mg
Answer:
= -4.2°C
= 49.4°C
Explanation:
A Carnot cycle is known as an ideal cycle in thermodynamic. Therefore, in theory, we have:
|
| = 
Similarly,
|
| = |
| + |
|
During winter, the value of |
| = 20°C = 273.15 + 20 = 293.15 K and |
| = 1.5 kW. Therefore,
|
| = 0.75(
-
)
Similarly,
|
| = 1 - 
1.5/0.75*(293.15-
) = 1 - (
/293.15
Further simplification,
= -4.2°C
During summer,
= 25°C = 273.15+25 = 298.15 K, and |
| = 1.5 kW. Therefore,
|
| = 0.75(
-
)
Similarly,
|
| =
- 1
1.5/0.75*(
- 298.15) = (
/298.15
Further simplification,
= 49.4°C