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Firlakuza [10]
3 years ago
6

An aqueous solution of perchloric acid is standardized by titration with a 0.191 M solution of barium hydroxide. If 13.8 mL of b

ase are required to neutralize 17.0 mL of the acid, what is the molarity of the perchloric acid solution?
Chemistry
1 answer:
WARRIOR [948]3 years ago
3 0

Answer:

Molarity of HClO_{4} solution is 0.311 M

Explanation:

Neutralization reaction: 2HClO_{4}+Ba(OH)_{2}\rightarrow Ba(ClO_{4})_{2}+2H_{2}O

According to balanced reaction, 1 mol of Ba(OH)_{2} neutralizes 2 moles of HClO_{4}

Number of moles of Ba(OH)_{2} in 13.8 mL of 0.191 M Ba(OH)_{2} solution = \frac{0.191}{1000}\times 13.8moles = 0.00264moles

Let's assume molarity of HClO_{4} solution is C (M) then-

Number of moles of HClO_{4} in 17.0 mL of C (M) HClO_{4} solution = \frac{C}{1000}\times 17.0moles = 0.017Cmoles

Hence, 0.017C=(2\times 0.00264)

         or, C=0.311

So, molarity of HClO_{4} solution is 0.311 M

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