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attashe74 [19]
3 years ago
8

The iron content of foods can be determined by dissolving them in acid (forming Fe3+), reducing the iron(III) to iron(II), and t

itrating with cerium(IV): Fe2+(aq) + Ce4+(aq) → Fe3+(aq) + Ce3+(aq). Identify the two half-reactions in the above reaction. oxidation half-reaction reduction half-reaction
Chemistry
1 answer:
____ [38]3 years ago
4 0

Answer:

  • <em>Oxidation half-reaction</em>:

Fe²⁺(aq) →  Fe³⁺(aq) + 1e⁻

  • <em>Reduction half-reaction</em>:

Ce⁴⁺(aq) + 1e⁻ →  Ce³⁺(aq)

Explanation:

The reaction that takes place is:

  • Fe²⁺(aq) + Ce⁴⁺(aq) → Fe³⁺(aq) + Ce³⁺(aq)

The <em>oxidation half-reaction</em> is:

  • Fe²⁺(aq) →  Fe³⁺(aq) + 1e⁻

It is an oxidation because the oxidation state of Fe increases from 2+ to 3+.

The <em>reduction half-reaction</em> is:

  • Ce⁴⁺(aq) + 1e⁻ →  Ce³⁺(aq)

It is a reduction because the oxidation state of Ce decreases from 4+ to 3+.

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3 years ago
A water solution contains 1.704 [kg] of HNO3 per [kg] of water, and has a specific gravity of 1.382 at 20 [°C]. Please, express
Rudik [331]

Answer:

(a) The weight percent HNO3 is 63%.

(b) Density of HNO3 = 111.2 lb/ft3

(c) Molarity = 13792 mol HNO3/m3

Explanation:

(a) Weight percent HNO3

To calculate a weight percent of a component of a solution we can express:

wt = \frac{mass \, of \, solute}{mass \, of \, solution}=\frac{mass\,HNO_3}{mass \, HNO_3+mass \, H_2O}\\  \\wt=\frac{1.704}{1.704+1} =\frac{1.704}{2.704}= 0.63

(b) Density of HNO3, in lb/ft3

In this calculation, we use the specific gravity of the solution (1.382). We can start with the volume balance:

V_s=V_{HNO3}+V_w\\\\\frac{M_s}{\rho_s}=\frac{M_{HNO3}}{\rho_{HNO3}}+\frac{M_w}{\rho_w}\\\\\frac{M_{HNO3}}{\rho_{HNO3}} = \frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}\\\\\rho_{HNO3}=\frac{M_{HNO3}}{\frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{\frac{2.704}{1.382*\rho_w}+\frac{1}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{2.956/ \rho_w}= 0.576*\rho_w[tex]V_s=V_{HNO3}+V_w\\\\\frac{M_s}{\rho_s}=\frac{M_{HNO3}}{\rho_{HNO3}}+\frac{M_w}{\rho_w}\\\\\frac{M_{HNO3}}{\rho_{HNO3}} = \frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}\\\\\rho_{HNO3}=\frac{M_{HNO3}}{\frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{\frac{2.704}{1.382*\rho_w}-\frac{1}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{0.956/\rho_w}= 1.782*\rho_w

The density of HNO3 is 1.782 times the density of water (Sp Gr of 1.782). If the density of water is 62.4 lbs/ft3,

\rho_{HNO3}= 1.782*\rho_w=1.782*62.4 \, lbs/ft3=111.2\, lbs/ft3

(c) HNO3 molarity (mol HNO3/m3)

If we use the molar mass of HNO3: 63.012 g/mol, we can say that in 1,704 kg (or 1704 g) of HNO3 there are  1704/63.012=27.04 mol HNO3.

When there are 1.704 kg of NHO3 in solution, the total mass of the solution is (1.704+1)=2.704 kg.

If the specific gravity of the solution is 1.382 and the density of water at 20 degC is 998 kg/m3, the volume of the solution is

Vol=\frac{M_{sol}}{\rho_{sol}}=\frac{2.704\, kg}{1.382*998 \, kg/m3} = 0.00196m3

We can now calculate the molarity as

Molarity HNO_3=\frac{MolHNO3}{Vol}=\frac{27.04mol}{0.00196m3}  =13792 \frac{molHNO3}{m3}

8 0
3 years ago
3. Why do some reactions occur Nturally, and others do not?
Serhud [2]

Answer:

depends

Explanation:

because some are caused by different variables

3 0
1 year ago
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