It all depends on the exact problem. Most hexagons have an interior of 60 degrees and an exterior of 120. Hope this helps!
Think about the fact that you can have two types of isosceles triangle: one of them that is a right triangle (isosceles right triangle) such as a 45-45-90 triangle and the other type can be just a regular triangle that has two sides that are congruent but it isn't a right triangle.
Thus, you would need more info about the triangles in order to conclude that the two isosceles triangles are congruent to each other.