Which of the following statements does NOT describe the anomeric carbon? A. This carbon is attached to two oxygens. B. This carb
on is chiral. C. The hydroxyl group on this carbon can be above or below the ring. D. It is the carbon of the carbonyl in the open-chain form of the sugar. E. All of the statements describe the anomeric carbon
1 answer:
Answer:
The answer is E. All of the statements describe the anomeric carbon.
Explanation:
When a sugar switches from its open form to its ring form, the carbon from the carbonyl (aldehyde if it is an aldose, or a ketone in the case of a ketose) suffers a nucleophilic addition by one of the hydroxyls in the chain, preferably one that will form a 5 or 6 membered ring after the reaction.
As such, the anomeric carbon will have two oxygens attached (The original one and the one that bonded when the ring closed).
It will be chiral, given that it has 4 different groups attached. (-OR,-OH,-H and -R, where R is the carbon chain).
The hydroxyl group can be in any position (Above of below the ring), depending on with side the addition took place. (See attachment)
It is the carbon of the carbonyl in the open-chain form of the sugar, because it is the only one that can react with the Hydroxyls.
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Answer:
a) [Ag+]dilute = 6.363 × 10⁻¹⁶ M
b) 1.273 × 10⁻¹⁶
c) 2.629×10⁻¹⁹ M Thus; the value for [Ag+ ]dilute will be too low
Explanation:
In an Ag | Ag+ concentration cell ,
The anode reaction can be written as :
Ag ----> Ag+(dilute) + e- &:
The cathode reaction can be written as:
Ag+(concentrated) + e- ----> Ag
The Overall Reaction : is
Ag+(concentrated) -----> Ag+(dilute)
However, the Standard Reduction potential of cell = E°cell = 0
( since both cathode and anode have same Ag+║Ag )
Also , given that the theoretical slope is - 0.0591 V
Therefore; the reduction potential of cell ; i.e
Ecell = E°cell - 0.0591 V × log ( [Ag+]dilute / [Ag+]concentrated )
0.839 V = 0 - 0.0591 V × log ( [Ag+]dilute / ( 1.0 × 10⁻¹ M ) )
log ( [Ag+]dilute / ( 1.0 × 10⁻¹ M ) ) = - 14.1963
[Ag+]dilute = × 1.0 × 10⁻¹ M
[Ag+]dilute = 6.363 × 10⁻¹⁶ M
b)
AgI ----> Ag + (dilute) + I⁻
So , Solubility product = Ksp = [Ag⁺]dilute × [I⁻]
= 6.363 × 10⁻¹⁶ M × 0.20 M
= 1.273 × 10⁻¹⁶
c) If s/he mistakenly uses 1.039 V as Ecell; then the value for [Ag+]dilute will be :
Ecell = E°cell - 0.0591 V × log ( [Ag+]dilute / [Ag+]concentrated )
1.039 V = 0 - 0.0591 V × log ( [Ag+]dilute / ( 1.0 × 10⁻¹ M ) )
log ( [Ag+]dilute / ( 1.0 × 10⁻¹ M ) ) = - 17.5804
[Ag+]dilute = × 1.0 × 10⁻¹ M
[Ag+]dilute = 2.629×10⁻¹⁹ M
Thus, the value for [Ag+ ]dilute will be too low