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lara31 [8.8K]
3 years ago
9

When a 2.00 g sample of KCl is dissolved in water in a calorimeter that has a total heat capacity of 1.28 kJ ⋅ K − 1 , the tempe

rature decreases by 0.360 K . Calculate the molar heat of solution of KCl .
Chemistry
1 answer:
Alchen [17]3 years ago
7 0

Answer : The molar heat of solution of KCl is, 17.19 kJ/mol

Explanation :

First we have to calculate the heat of solution.

q=c\times (\Delta T)

where,

q = heat produced = ?

c = specific heat capacity of water = 1.28kJ/K

\Delta T = change in temperature = 0.360 K

Now put all the given values in the above formula, we get:

q=1.28kJ/K\times 0.360K

q=0.4608kJ=460.8J

Now we have to calculate the molar heat solution of KCl.

\Delta H=\frac{q}{n}

where,

\Delta H = enthalpy change = ?

q = heat released = 460.8 J

m = mass of KCl = 2.00 g

Molar mass of KCl = 74.55 g/mol

\text{Moles of }KCl=\frac{\text{Mass of }KCl}{\text{Molar mass of }KCl}=\frac{2.00g}{74.55g/mole}=0.0268mole

Now put all the given values in the above formula, we get:

\Delta H=\frac{460.8J}{0.0268mole}

\Delta H=17194.029J/mol=17.19kJ/mol

Therefore, the molar heat of solution of KCl is, 17.19 kJ/mol

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