Answer:
CN^- is a strong field ligand
Explanation:
The complex, hexacyanoferrate II is an Fe^2+ specie. Fe^2+ is a d^6 specie. It may exist as high spin (paramagnetic) or low spin (diamagnetic) depending on the ligand. The energy of the d-orbitals become nondegenerate upon approach of a ligand. The extent of separation of the two orbitals and the energy between them is defined as the magnitude of crystal field splitting (∆o).
Ligands that cause a large crystal field splitting such as CN^- are called strong field ligands. They lead to the formation of diamagnetic species. Strong field ligands occur towards the end of the spectrochemical series of ligands.
Hence the complex, Fe(CN)6 4− is diamagnetic because the cyanide ion is a strong field ligand that causes the six d-electrons present to pair up in a low spin arrangement.
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Answer:
1.84 L
Explanation:
Using the equation for reversible work:

Where:
W is the work done (J) = -287 J.
Since the gas did work, therefore W is negative.
P is the pressure in atm = 1.90 atm.
However, work done is in joules and pressure is in atm. We can use the values of universal gas constant as a convenient conversion unit. R = 8.314 J/(mol*K); R = 0.0821 (L*atm)/(mol*K)
Therefore, the conversion unit is 0.0821/8.314 = 0.00987 (L*atm)/J
is the initial volume = 0.350 L
is the final volume = ?
Thus:
(-287 J)*0.00987 (L*atm)/J = -1.9 atm*(
- 0.350) L
= [(287*0.00987)+(1.9*0.350)]/1.9 = (2.833+0.665)/1.9 =1.84 L
Answer:
A. Warning
Explanation:
Out of all said choices, the best choice would be warning since it would fit the sentence the most.
"A Warning notifies you that danger is present." compared to:
"A Hazard notifies you that danger is present."
"A Safety notifies you that danger is present."
"A Danger notifies you that danger is present."
Answer:
2 moles
Explanation:
The following were obtained from the question:
Molarity = 0.25 M
Volume = 8L
Mole =?
Molarity is simply defined as the mole of solute per unit litre of solution. It is represented mathematically as:
Molarity = mole of solute/Volume of solution.
With the above equation, we can easily find the number of mole of MgCl2 present in 8 L of 0.25 M MgCl2 solution as follow:
Molarity = mole of solute/Volume of solution.
0.25 = mole of MgCl2 /8
Cross multiply to express in linear form
Mole of MgCl2 = 0.25 x 8
Mole of MgCl2 = 2 moles
Therefore, 2 moles of MgCl2 are present in 8 L of 0.25 M MgCl2 solution