Answer:
The final temperature is equal to 240 K or -33.15°C
Explanation:
Given that,
Initial temperature of the gas, T₁ = 47°C = 320 K
Initial pressure, P₁ = 140 kpa
Final pressure, P₂ = 105 kpa
We need to find the final temperature if the volume remains constant. The relation between temperature and pressure is given by :

or

So, the final temperature is equal to 240 K or -33.15°C.
M(P)=3.72 g
M(P)=31 g/mol
m(Cl)=21.28 g
M(Cl)=35.5 g/mol
n(P)=m(P)/M(P)
n(P)=3.72/31=0.12 mol
n(Cl)=m(Cl)/M(Cl)
n(Cl)=21.28/35.5=0.60 mol
P : Cl = 0.12 : 0.60 = 1 : 5
PCl₅ - is the empirical formula