The equation given in question is as follow,
ZnS + NO₃⁻ → Zn²⁺ + S + NO
Oxidation state of elements in reactant side are as follow,
Zn = +2
S = -2
N = +5
O = -2
Oxidation state of elements in product side are as follow,
Zn = +2
S = 0
N = +2
O = -2
So, In this reaction Nitrogen is Reduced while Sulfur is Oxidized.
Now Split the reaction into two half cell reactions,
Reduction Reaction,
ZnS → S + 2e⁻
Oxidation Reaction,
NO₃⁻ + 3e⁻ → NO
As the oxygen atoms are not balance, So, in acidic medium add H⁺ on the side having greater number of Oxygen atom and H₂O on the side having less number of Oxygen atoms,
Hence,
H⁺ + NO₃⁻ + 3e⁻ → NO + H₂O
Now Balance the reaction,
4H⁺ + NO₃⁻ + 3e⁻ → NO + 2H₂O
So, write both half cell equations as,
ZnS → S + 2e⁻ --------- (1)
4H⁺ + NO₃⁻ + 3e⁻ → NO + 2H₂O -------(2)
Multiply eq. 1 with 3 and eq. 2 with 2 to equalize the electron.
So,
3ZnS → 3S + 6e⁻
8H⁺ + 2NO₃⁻ + 6e⁻ → 2NO + 4H₂O
_____________________________________(e⁻ cancelled)
3ZnS + 2NO₃⁻ + 8H⁺ → 3Zn + 3S + 2NO + 4H₂O
Answer:
Butan-2-one
Explanation:
1. 1700 cm⁻¹
A strong peak near 1700 cm⁻¹ is almost certainly a carbonyl (C=O) group.
2. Triplet-quartet
A triplet-quartet pattern indicates an ethyl group.
The 2H quartet is a CH₂ adjacent to a CH₃. The peak normally occurs at δ 1.3, but it is shifted 1.2 ppm downfield to δ 2.47 by an adjacent C=O group.
The 3H triplet at δ 1.05 is the methyl group. It, too, is shifted downfield from its normal position at δ 0.9. The effect is smaller, because the methyl group is further from the carbonyl.
3. 3H(s) at δ 2.13
This indicates a CH₃ group with no adjacent hydrogen atoms.
It is shifted 0.8 ppm downfield to δ 2.13 by the adjacent C=O group.
4. Identification
The identified pieces are CH₃CH₂-, -(CO)-, and -CH₃. There is only one way to put them together: CH₃CH₂-(C=O)-CH₃.
The compound is butan-2-one.
Answer:
Explanation:
The oxidation reduction reactions are called redox reaction. These reactions are take place by gaining or losing the electrons and oxidation state of elements are changed.
Oxidation:
Oxidation involve the removal of electrons and oxidation state of atom of an element is increased.
Reduction:
Reduction involve the gain of electron and oxidation number is decreased.
Oxidizing agents:
Oxidizing agents oxidize the other elements and itself gets reduced.
Reducing agents:
Reducing agents reduced the other element are it self gets oxidized.
In given example,
Magnesium is able to <u>reduced</u> the copper and copper is able to <u>oxidized</u> the magnesium.
Zinc is able to <u>oxidized</u> the magnesium and magnesium is able to <u>reduced</u> the zinc.
Copper is able to <u>oxidized</u> the zinc and zinc is able to <u>reduced</u> the copper.
Answer:
See explanation
Explanation:
Specific activity of an enzyme is defined as a measure of the rate of reaction between enzyme and substrate.
In the study of enzyme kinetics, specific activity is particularly regarded to be the amount of substrate converted by the enzyme per milligram of protein per unit of time. It is thus a reliable measure of enzyme activity per milligram of total protein.
On the other hand, the turnover number is defined as a measure of the number of conversions achieved by a substrate molecule in one second at a particular active site depending on the specific enzyme concentration.
Since specific activityof the enzyme is the ratio of the enzyme activity to enzyme concentration, then specific activity can be used as a measurement of enzyme purity.
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