The biological process that directly converts energy from the Sun into chemical energy would be Photosynthesis. It is a process carried out by autotrophic organisms which are predominantly plants and other photosynthetic bacteria.
Most likely solid. Molecules move in a chaotic matter, which a Scottish botanist found out in the 19th century. In gases, this chaotic movement is the most “dramatic” and they move around freely; in liquids it’s a bit less noticeable, and in solids the particles oscillate around locked positions. Movement in plasma is similar to gas.