Answer:
![[Pb^{2+}]=3.9 \times 10^{-2}M](https://tex.z-dn.net/?f=%5BPb%5E%7B2%2B%7D%5D%3D3.9%20%5Ctimes%2010%5E%7B-2%7DM)
this is the concentration required to initiate precipitation
Explanation:
⇄
Precipitation starts when ionic product is greater than solubility product.
Ip>Ksp
Precipitation starts only when solution is supersaturated because solution become supersaturated then it does not stay in this form and precipitation starts itself only solution become saturated.
This usually happens when two solutions containing separate sources of cation and anion are mixed together and here also we are mixing lead (||)nitrate solution(source of lead(||)) into the Cl- solution.
![Ip=[Pb^{2}][2Cl^-]^2=Ksp](https://tex.z-dn.net/?f=Ip%3D%5BPb%5E%7B2%7D%5D%5B2Cl%5E-%5D%5E2%3DKsp)

lets solubility=S
![[Pb^{2+}] = S](https://tex.z-dn.net/?f=%5BPb%5E%7B2%2B%7D%5D%20%3D%20S)
![[Cl^-]=2S](https://tex.z-dn.net/?f=%5BCl%5E-%5D%3D2S)
![Ksp=[Pb^{2+}]\times [Cl^-]^2](https://tex.z-dn.net/?f=Ksp%3D%5BPb%5E%7B2%2B%7D%5D%5Ctimes%20%5BCl%5E-%5D%5E2)


![S=\sqrt[3]{\frac{Ksp}{4} }](https://tex.z-dn.net/?f=S%3D%5Csqrt%5B3%5D%7B%5Cfrac%7BKsp%7D%7B4%7D%20%7D)

this is the concentration required to initiate precipitation
Answer:
for given question is 2.79 and
is 0.52
{i- vant hoff’s constant ; Kb- constant ; m molarity }
M = no. of moles of the solute present in one kg of solution
Let the weight of amount of solute be “w” and its molecular mass be “M”
Let the mass of the solvent in the given question be “x”




Yes, depending on the thickness.