Answer:
a. 3-methylbutan-2-ol
b. 2-methylcyclohexan-1-ol
Explanation:
For this reaction, we must remember that the hydroboration is an <u>"anti-Markovnikov" reaction</u>. This means that the "OH" will be added at the <em>least substituted carbon of the double bond.</em>
In the case of <u>2-methyl-2-butene</u>, the double bond is between carbons 2 and 3. Carbon 2 has two bonds with two methyls and carbon 3 is attached to 1 carbon. Therefore <u>the "OH" will be added to carbon three</u> producing <u>3-methylbutan-2-ol</u>.
For 1-methylcyclohexene, the double bond is between carbons 1 and 2. Carbon 1 is attached to two carbons (carbons 6 and 7) and carbon 2 is attached to one carbon (carbon 3). Therefore<u> the "OH" will be added to carbon 2</u> producing <u>2-methylcyclohexan-1-ol</u>.
See figure 1
I hope it helps!
Answer:
24 atm is the total pressure exerted by the gases
Explanation:
We propose this situation:
In a vessel, we have 4 gases (for example, hydrogen, Xe, methane and chlorine)
Each of the gases has the same pressure:
6 atm → hydrogen
6 atm → xenon
6 atm → methane
6 atm → chlorine
To determine the total pressure, we sum all of them:
Partial pressure H₂ + Partial pressure Xe + Partial pressure CH₄ + Partial pressure Cl₂ = Total P
6 atm + 6 atm + 6 atm + 6 atm = 24atm
Answer:
8.37 grams
Explanation:
The balanced chemical equation is:
C₆H₁₂O₆ ⇒ 2 C₂H₅OH (l) + 2 CO₂ (g)
Now we are asked to calculate the mass of glucose required to produce 2.25 L CO₂ at 1atm and 295 K.
From the ideal gas law we can determine the number of moles that the 2.25 L represent.
From there we will use the stoichiometry of the reaction to determine the moles of glucose which knowing the molar mass can be converted to mass.
PV = nRT ⇒ n = PV/RT
n= 1 atm x 2.25 L / ( 0.08205 Latm/kmol x 295 K ) =0.093 mol CO₂
Moles glucose required:
0.093 mol CO₂ x ( 1 mol C₆H₁₂O₆ / 2 mol CO₂ ) = 0.046 mol C₆H₁₂O₆
The molar mass of glucose is 180.16 g/mol, then the mass required is
0.046 mol x 180.16 g/mol = 8.37 g
