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tankabanditka [31]
3 years ago
15

A gas mixture with a total pressure of 745 mmHg contains each of the following gases at the indicated partial pressures: CO2, 12

5 mmHg; Ar, 214 mmHg; and O2, 187 mmHg. The mixture also contains helium gas. What is the partial pressure of the helium gas? What mass of helium gas is present in a 12.0-L sample of this mixture at 273 K?
Chemistry
1 answer:
Serhud [2]3 years ago
7 0

Answer:

P_{He}=219mmHg

m_{He}=0.618gHe

Explanation:

Hello,

By applying the Dalton's law, we can compute the partial pressure of the helium has:

P_{tot}=P_{CO_2}+P_{Ar}+P_{O_2}+P_{He}

Now, solving for the partial pressure of the helium gas we get:

P_{He}=P_{tot}-P_{CO_2}-P_{Ar}-P_{O_2}=745mmHg-125mmHg-214mmHg-187mmHg\\P_{He}=219mmHg=0.288atm

On the other hand, the mass of the helium gas is computed via the ideal gas equation in terms of the helium's mass:

PV=\frac{m_{He}}{M_{He}}RT\\m_{He}=\frac{M_{He}PV}{RT} =\frac{4g/mol*0.288atm*12L}{0.082\frac{atm*L}{mol*K}*273K}\\ m_{He}=0.618gHe

Best regards.

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<em> Is given 250mL of a 1.60M chlorous acid HClO2 solution. Ka is 1.110x10⁻². What mass of NaClO₂ should the student dissolve in the HClO2 solution to turn it into a buffer with pH =1.45? </em>

It is possible to answer this question using Henderson-Hasselbalch equation:

pH = pKa + log₁₀ [A⁻] / [HA]

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You can change the concentration of the substance if you write the moles of the substances:

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Replacing in H-H expression, as the pH you want is 1.45:

1.45 = 1.9547 + log₁₀ [Moles NaClO₂] / [0.40 moles HClO₂]

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<em>0.3128 = </em>[Moles NaClO₂] / [0.40 moles HClO₂]

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0.1251 moles NaClO₂ ₓ (90.44g / mol) =

<h3>11.31g NaClO₂</h3>
5 0
3 years ago
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