The answers are :
1 - F
2- T
Explanation:
Reaction equation is as follows.

Here, 1 mole of
produces 2 moles of cations.
![[Na^{+}] = 2[Na_{2}SO_{3}] = 2 \times 0.58](https://tex.z-dn.net/?f=%5BNa%5E%7B%2B%7D%5D%20%3D%202%5BNa_%7B2%7DSO_%7B3%7D%5D%20%3D%202%20%5Ctimes%200.58)
= 1.16 M
= 0.58 M
The sulphite anion will act as a base and react with
to form
and
.
As, 
= 
=
According to the ICE table for the given reaction,

Initial: 0.58 0 0
Change: -x +x +x
Equilibrium: 0.58 - x x x
So,
![K_{b} = \frac{[HSO^{-}_{3}][OH^{-}]}{[SO^{2-}_{3}]}](https://tex.z-dn.net/?f=K_%7Bb%7D%20%3D%20%5Cfrac%7B%5BHSO%5E%7B-%7D_%7B3%7D%5D%5BOH%5E%7B-%7D%5D%7D%7B%5BSO%5E%7B2-%7D_%7B3%7D%5D%7D)


x = 0.0003 M
So, x =
= 0.0003 M
= 0.58 - 0.0003
= 0.579 M
Now, we will use
= 0.0003 M
The reaction will be as follows.

Initial: 0.0003
Equilibrium: 0.0003 - x x x


= 
= 
Therefore, 
As, x <<<< 0.0003. So, we can neglect x.
Therefore, 
= 
x = 
x =
= 
![[H^{+}] = \frac{10^{-14}}{[OH^{-}]}](https://tex.z-dn.net/?f=%5BH%5E%7B%2B%7D%5D%20%3D%20%5Cfrac%7B10%5E%7B-14%7D%7D%7B%5BOH%5E%7B-%7D%5D%7D)
= 
=
M
Thus, we can conclude that the concentration of spectator ion is
M.
Answer:
balanced in ACID not BASE
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
Answer
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
Explanation:
Cr2O7^2-(aq) + Hg(l) ----> Hg^2+(aqH) + Cr^3+(aq)
add H^1+ (acid) to capture the O and make 7 water molecules
Cr2O7^2-(aq) + Hg(l) + H^1+ ----> Hg^2+(aqH) + Cr^3+(aq) + 7H2O
Cr goes from +6 to +3 by gaining 3 e
Hg goes from 0 to +2 by losing 2 e
we need 3 Hg for every 2 Cr
so
Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O
2 Cr on the right and left
Net 12 positive charges on the right and the left
3 Hg on the right and left
14 H on the right and left
the equation is balanced
we cannot balance the equation in a basic solution with OH^1-
we have plenty of O in the dichromate ion. we need to convert it to water which take free H^1+ from the acid
N=m(g)/m.wt
n=85/12(1)+16(2) =1.93 moles