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Vaselesa [24]
3 years ago
9

For a reaction for which AH = +29.3 kJ/mol and AS = +106 J/mol•K, which of the following statements is true? A) The reaction is

spontaneous above 276 K. B) The reaction is spontaneous below 276 K. C) The reaction will never reach equilibrium. D) The reaction will never be spontaneous.
Chemistry
1 answer:
umka2103 [35]3 years ago
8 0

Answer: A) The reaction is spontaneous above 276 K.

Explanation:

According to Gibb's equation:

\Delta G=\Delta H-T\Delta S

\Delta G = Gibbs free energy  

\Delta H = enthalpy change  = +29.3 kJ/mol =29300 J/mol

\Delta S = entropy change  = +106 J/molK

T = temperature in Kelvin

\Delta G= +ve, reaction is non spontaneous

\Delta G= -ve, reaction is spontaneous

\Delta G= 0, reaction is in equilibrium

\Delta G=(+ve)-T(+ve)

\Delta G=(+ve)(-ve)

T\Delta S>\Delta H  for reaction to be spontaneous

T\times 106 J/molK>29300J/mol

T>276K

Thus the Reaction is spontaneous when temperature is above 276 K.

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<u />

Explanation:

Step 1: The balanced equation

Fe2S3 + 6HCl → 3H2S + 2FeCl3

Step 2:

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<u />

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Double - displacement reaction: This is a reaction in which the positive and negative ions of two ionic compounds exchange places to form two new compounds. The general form of a double-replacement (also called double-displacement) reaction is:

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In this reaction,  A  and  C  are positively-charged cations, while  B  and  D  are negatively-charged anions. Double-replacement reactions generally occur between substances in aqueous solution. In order for a reaction to occur, one of the products is usually a solid precipitate, a gas, or a molecular compound such as water.

In our case: There occurs a duble replacement between Fe^3+ and S^2- with H+ and Cl-.

<u>Fe2S3 + 6HCl → 3H2S + 2FeCl3 is a double-displacement  reaction</u>

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The current atomic theory can best be described as the most powerful explanation scientists have to offer at this time.

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