Given the data in the accompanying table, what is the reaction order for B?
2 answers:
Answer: The order with respect to B is
Explanation: Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.
k= rate constant
x = order with respect to A
y = order with respect to B
n = x+y = Total order
a) From trial 1: (1)
From trial 2: (2)
Dividing 2 by 1 :
therefore y=1.
Thus order with respect to B is 1.
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<u>Answer:</u> The correct statement is low temperature only, because entropy decreases during freezing.
<u>Explanation:</u>
The relationship between Gibb's free energy, enthalpy, entropy and temperature is given by the equation:
Where,
= change in Gibb's free energy
= change in enthalpy
T = temperature
= change in entropy
It is given that freezing of methane is taking place, which means that entropy is decreasing and is becoming negative. It is also given that the reaction is an exothermic reaction, this means that the
is also negative.
For a reaction to be spontaneous, must be negative.
From above equations, it is visible that will be negative only when the temperature will be low.
Hence, the correct statement is low temperature only, because entropy decreases during freezing.