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2 years ago

Which answer best defines physical property

Chemistry

1 answer:

yulyashka [42]2 years ago

8 0

Any property that is measurable, whose value describes a state of a physical system.

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Suppose you have just added 100 ml of a solution containing 0.5 mol of acetic acid per liter to 400 ml of 0.5 m naoh. what is th

Tpy6a [65]

$pH = 13.5$

Explanation:

Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:

$\text{HAc} + \text{OH}^{-} \to \text{Ac}^{-} + \text{H}_2\text{O}$

The mixture would contain

$0.4 \times 0.5 - 0.1 \times 0.5 = 0.15 \; \text{mol}$ of $\text{OH}^{-}$ and
$0.1 \times 0.5 = 0.05 \; \text{mol}$ of $\text{Ac}^{-}$

if $\text{Ac}^{-}$ undergoes no hydrolysis; the solution is of volume $0.1 + 0.4 = 0.5 \; \text{L}$ after the mixing. The two species would thus be of concentration $0.30 \; \text{mol} \cdot \text{L}^{-1}$ and $0.10 \; \text{mol} \cdot \text{L}^{-1}$ , respectively.

Construct a RICE table for the hydrolysis of $\text{Ac}^{-}$ under a basic aqueous environment (with a negligible hydronium concentration.)

$\begin{array}{cccccccc} \text{R} & \text{Ac}^{-}(aq) &+ & \text{H}_2\text{O}(aq) & \leftrightharpoons & \text{HAc}(aq) & + & \text{OH}^{-} (aq)\\ \text{I} & 0.10 \; \text{M} & & & & & &0.30 \; \text{M}\\ \text{C} & -x \; \text{M}& & & & +x \; \text{M}& & +x \; \text{M} \\ \text{E} & (0.10 - x) \; \text{M} & & & & x \; \text{M} & & (0.30 +x) \; \text{M} \end{array}$

The question supplied the acid dissociation constant $pK_a$ for acetic acid $\text{HAc}$ ; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the base dissociation constant $pK_b$ for its conjugate base, $\text{Ac}^{-}$ . The following relationship relates the two quantities:

$pK_{b} (\text{Ac}^{-}) = pK_{w} - pK_{a}( \text{HAc})$

... where the water self-ionization constant $pK_w \approx 14$ under standard conditions. Thus $pK_{b} (\text{Ac}^{-}) = 14 - 4.7 = 9.3$ . By the definition of $pK_b$ :

$[\text{HAc} (aq)] \cdot [\text{OH}^{-} (aq)] / [\text{Ac}^{-} (aq) ] = K_b = 10^{-pK_{b}}$

$x \cdot (0.3 + x) / (0.1 - x) = 10^{-9.3}$

$x = 1.67 \times 10^{-10} \; \text{M} \approx 0 \; \text{M}$

$[\text{OH}^{-}] = 0.30 +x \approx 0.30 \; \text{M}$

$pH = pK_{w} - pOH = 14 + \text{log}_{10}[\text{OH}^{-}] = 14 + \text{log}_{10}{0.30} = 13.5$

6 0

2 years ago

Where digestion take place in : ( carbohydrates ) ( fats ) ( proteins )

garri49 [273]

Answer:

Digestion take place in Fats.

7 0

2 years ago

Which product forms from the synthesis reaction between lithium (Li) and oxygen (O)?

Advocard [28]

Answer:

A Li2O

Explanation:

Li has a 1+ charge and O has a 2- charge so to balance the charges there needs to be 2 Li for every 1 O

5 0

2 years ago

Calculate the mass of khc8h4o4 that reacts with 15 ml of the naoh solution

dlinn [17]

The balanced chemical reaction would be:

KHC8H4O4 (aq) + NaOH (aq) → NaKC8H4O4 (aq) + H2O.

The concentration of the NaOH is equal 0.1 M. We use this and the volume given above to determine the mass of KHC8H4O4. We do as follows:

0.1 mol / L NaOH (.015 L) ( 1 mol KHC8H4O4 / 1 mol NaOH) (204 g / 1 mol) = 0.306 g KHC8H4O4

6 0

3 years ago

15.0 moles of gas are in a 8.00 L tank at 22.3 ∘C∘C . Calculate the difference in pressure between methane and an ideal gas unde

leva [86]

Answer:

$\Delta P=4.10atm$

Explanation:

Hello!

In this case, since the ideal gas equation is used under the assumption of no interaction between molecules and perfectly sphere-shaped molecules but the van der Waals equation actually includes those effects, we can compute each pressure as shown below, considering the temperature in kelvins (22.3+273.15=295.45K):

$P^{ideal}=\frac{nRT}{V}=\frac{15.0mol*0.08206\frac{atm*L}{mol*K}*295.45K}{8.00L}=45.5atm$

Next, since the VdW equation requires the molar volume, we proceed as shown below:

$v=\frac{8.00L}{15.0mol}=0.533\frac{L}{mol}$

Now, we use its definition:

$P^{VdW}=\frac{RT}{v-b} -\frac{a}{v^2}$

Thus, by plugging in we obtain:

$P^{VdW}=\frac{0.08206\frac{atm*L}{mol*K}*295.45K}{0.533mol/L-0.0430L/mol} -\frac{2.300L^2*atm/mol^2}{(0.533L/mol)^2}\\\\P^{VdW}=49.44atm-8.09atm\\\\P^{VdW}=41.4atm$

Thus, the pressure difference is:

$\Delta P=45.5atm-41.4atm\\\\\Delta P=4.10atm$

Best regards!

6 0

2 years ago