I am pretty sure it’s D.Sulfur
Ba²⁺ + 2Cl⁻ + 2H⁺ + SO₄²⁻ = BaSO₄ (precipitate) + 2H⁺ + 2Cl⁻
Ba²⁺ + SO₄²⁻ = BaSO₄
In general, solubility increases with temperature. When you increase the temperature of a solvent, you increase the kinetic energy (or energy of movement) of the molecules, and this greater energy helps dissolve more of the solute molecules.
A is correct because there is no reaction involved