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Dmitrij [34]
3 years ago
13

In the reaction 5 space B r to the power of minus space (a q )space plus space B r O subscript 3 to the power of minus space (a

q )space plus space 6 space H to the power of plus space (a q )space rightwards arrow space 3 space B r subscript 2 space (a q )space plus space 3 space H subscript 2 O space (l )the rate of disappearance of Br- at some moment in time was determined to be 3.5 x 10-4 M/s. What is the rate of appearance of Br2 at that same moment
Chemistry
1 answer:
Rainbow [258]3 years ago
6 0

Answer:

r_{Br_2}=2.1x10^{-4}M/s

Explanation:

Hello,

In this case, for the reaction:

5Br^-(aq)+BrO_3^-(aq)+6H^+(aq)\rightarrow 3Br_2(aq)+3H_2O(l)

Thus, via the rate proportions between Br⁻ and Br₂ for which the stoichiometric coefficients are 5 and 3 respectively, we can write:

\frac{r_{Br^-}}{-5} =\frac{r_{Br_2}}{3}

Hence, the rate of appearance of Br₂ turns out:

r_{Br_2}=\frac{3r_{Br^-}}{-5}=\frac{3*-3.5x10^{-4}M/s}{-5}\\ \\r_{Br_2}=2.1x10^{-4}M/s

Take into account that the rate of disappearance is negative for reactants.

Best regards.

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Explanation:

Entropy is defined as the degree of randomness present in a substance. Therefore, more is the irregularity present in a compound more will be its molar entropy.

Hence, decreasing order to molar entropy in state of matter is as follows.

                     Gases > Liquids > Solids

  • In the first pair, we are given Br_{2}(l) or Cl_{2}(g). Since, molar entropy of liquids is less than the molar entropy of gases.

Hence, Cl_{2}(g) will have larger molar entropy as compared to Br_{2}(l).

  • In the second pair, we are given Fe(s) or Ni(s). More is the molar mass of a compound more will its molar entropy. Molar mass of Fe is 55.84 g/mol and molar mass of Ni is 58.69 g/mol.

Hence, molar entropy of Ni(s) is more than the molar entropy of Fe(s).

  • In the third pair, we are given C_{2}H_{6}(g) or C_{2}H_{4}(g). As both the given species are gaseous in nature. So, more is the molar mass of specie more will be its molar entropy.

Molar mass of C_{2}H_{6}(g) is 30.07 g/mol and molar mass of C_{2}H_{4}(g) is 28.05 g/mol. Therefore, molar entropy of C_{2}H_{6}(g) is more than the molar entropy of C_{2}H_{4}(g).

  • In the fourth pair, we are given CCl_{4}(g) or CH_{4}(g). Molar mass of CCl_{4}(g) is 153.82 g/mol and molar mass of CH_{4}(g) is 16.04 g/mol.

Therefore, molar entropy of CCl_{4}(g) is more than the molar entropy of CH_{4}(g).

  • In the fifth pair, we are given HgO(s) or MgO(s). Molar mass of HgO is 216.59 g/mol and molar mass of MgO is 40.30 g/mol.

Hence, molar entropy of HgO(s) is more than the molar entropy of MgO.

  • In the fifth pair, we are given NaCl(aq) or MgCl_{2}(aq). Molar mass of NaCl 58.44 g/mol and molar mass of MgCl_{2}(aq) is 95.21 g/mol.

Hence, the molar entropy of MgCl_{2}(aq) is more than the molar entropy of NaCl(aq).

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All of the statements regarding the symbol "ΔH" are correct except it
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Answer: Option (D) is the correct answer.

Explanation:

Enthalpy is defined as the amount of energy needed or removed from a substance. It is represented by \Delta H.

Basically, it is the change in enthalpy and it represents the difference between the energy used in breaking bonds and the energy released in formation of bonds in a chemical reaction.

It is also known as heat of reaction. When value of \Delta H is positive then it means heat is absorbed in the chemical reaction.

When value of \Delta H is negative then it means that heat is released in the chemical reaction.

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When 1 mole of Zn and 2 mole of O₂ reacts togethor, It will produce 1 mole of ZnO as O₂ is excess reagent and Zn will act as Limiting reagent and thus it limits the amount of product formed.

<h3>What is Limiting reagent ?</h3>

Limiting reagents are the substances that are completely consumed first in a chemical reaction.

Given ;

  • Amopunt of Zn : 1 mole
  • Amount of O₂ : 2 mole

Given equation ;

2Zn + O₂ --> 2ZnO

As according to given chemical equation,

2 moles Zn of reacts with 1 mole of O₂ to produce 2 moles of ZnO.

Therefore,

1 mole of Zn will require 0.5 mole of O₂.

But,

the given amount of O₂ is 2 mole which is excess

Hence,

Zn here will act as the Limiting reagent, According to which the amount of product formed will be decided.

Therefore,

If 2 mole Zn produces : 2 moles of ZnO (According to given balanced equation)

Thus,

1 mole of Zn will produce = 2/2 x 1

                                          = 1 mole of ZnO

Hence, When 1 mole of Zn and 2 mole of O₂ reacts togethor, It will produce 1 mole of ZnO as O₂ is excess reagent and Zn will act as Limiting reagent and thus it limits the amount of product formed.

Learn more about Limiting reagent here ;

brainly.com/question/11848702

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