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RSB [31]
3 years ago
12

Read the chemical equation.

Chemistry
2 answers:
alekssr [168]3 years ago
7 0

<u>Answer:</u> The volume of ammonia produced is 0.8 L

<u>Explanation:</u>

At STP:

1 mole of a gas occupies 22.4 L of volume

We are given:

Volume of nitrogen gas = 1.2 L

For the given chemical reaction:

N_2(g)+3H_2(g)\rightarrow 2NH_3(g)

As, nitrogen gas is given in excess, it is considered as excess reagent. And, hydrogen gas is considered as the limiting reagent because it limits the formation of product.

By Stoichiometry of the reaction:

(3 × 22.4) L of hydrogen gas produces (2 × 22.4) L of ammonia

So, 1.2 L of hydrogen gas will produce \frac{(2\times 22.4)}{(3\times 22.4)}\times 1.2=0.8L of ammonia

Hence, the volume of ammonia produced is 0.8 L

Alex3 years ago
4 0

Answer : The volume of NH_3 produced is, 0.8 liters

Explanation :

The balanced chemical reaction will be,

N_2+3H_2\rightarrow 2NH_3

The mole ratio of nitrogen, hydrogen and ammonia are 1 : 3 : 2.

According to the Avogadro's Law, the volume is directly proportional to the number of moles of the gas at constant pressure and temperature.

V\propto n   (At constant temperature and pressure)

or,

\frac{V_1}{V_2}=\frac{n_1}{n_1}

where,

V_1 = volume of hydrogen = 1.2 L

V_2 = volume of ammonia = ?

n_1 = moles of hydrogen = 3 mole

n_2 = moles of ammonia = 2 mole

Now put all the given values in the above formula, we get the volume of ammonia.

\frac{1.2L}{V_2}=\frac{3mole}{2mole}

V_2=0.8L

Therefore, the volume of NH_3 produced is, 0.8 liters

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The buffer solution target has a pH value smaller than that of pKw (i.e., pH < 7.) The solution is therefore acidic. It contains significantly more protons \text{H}^{+} than hydroxide ions \text{OH}^{-}. The equilibrium equation shall thus contain protons rather than a combination of water and hydroxide ions as the reacting species.

Assuming that x \; \text{L} of the 0.307 \text{mol} \cdot \text{dm}^{-3} sodium hydroxide solution was added to the acetic acid. Based on previous reasoning, x is sufficiently small that acetic acid was in excess, and no hydroxide ion has yet been produced in the solution. The solution would thus contain 0.2000 \times 0.425 - 0.307 \; x = 0.085 - 0.307 \; x moles of acetic acid and 0.307 \; x moles of acetate ions.

Let \text{HAc} denotes an acetic acid molecule and \text{Ac}^{-} denotes an acetate ion. The RICE table below resembles the hydrolysis equilibrium going on within the buffer solution.

\begin{array}{lccccc}\text{R} & \text{HAc} & \leftrightharpoons & \text{H}^{+} & + & \text{Ac}^{-}\\\text{I} & 0.085 - 0.307 \; x& & 0 & & 0.307 \; x\\\end{array}

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\begin{array}{lcccccc}\text{R} & \text{HAc} & \leftrightharpoons & \text{H}^{+} & + & \text{Ac}^{-}\\\text{I} & 0.085 - 0.307 \; x& & 0 & & 0.307 \; x\\\text{C} & - 10^{-4.250} & & +10^{-4.250} & & +10^{-4.250} \\\text{E} & 0.085 - 10^{-4.250} - 0.307 \; x& & 10^{-4.250} & & 10^{-4.250} + 0.307 \; x\end{array}

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\text{K}_{a} = [\text{H}^{+}] \cdot [\text{Ac}^{-}] / [\text{HAc}]\\\phantom{\text{K}_{a}} = 10^{-4.250} \times (10^{-4.250} + 0.307 \; x) / (0.085 - 10^{-4.250} - 0.307 \; x)

The question states that

\text{K}_{a} = 1.75 \times 10^{-5}

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10^{-4.250} \times (10^{-4.250} + 0.307 \; x) / (0.085 - 10^{-4.250} - 0.307 \; x) = 1.75 \times 10^{-5}\\6.16 \times 10^{-5} \; x = 1.48 \times 10^{-6}\\x = 0.0241

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