Answer : The new volume of the balloon is, 22.4 L
Explanation :
Charles' Law : It is defined as the volume of gas is directly proportional to the temperature of the gas at constant pressure and number of moles.

or,

where,
= initial volume of gas = 22.6 L
= final volume of gas = ?
= initial temperature of gas = 
= final temperature of gas = 
Now put all the given values in the above formula, we get the final volume of the gas.


Therefore, the new volume of the balloon is, 22.4 L
Answer: a. 0.75m (NH4)3PO4 will have the lowest freezing point .
Explanation: Freezing point decreases as the concentration of the solute substance increases. Assuming the same solvent for all of them, for instance water.
∆T= i.Kf.b
∆T= freezing point depression
i= vant Hoff factor
Kf= molality
Assuming water to be the solvent for all Kf=1.86°C/M
VANT HOFF FACTORS :
For (NH4)3PO4
This has 3 ionic bonding and 1 covalent bonding making it 4 bond
Therefore i=4
For CaSO4
This has 1 metallic bond and 1 covalent bond making it 2 bond.
Therefore i=2
For LiCl
This has 1 metallic bond and 1 non metallic bond making it 2 bond.
Therefore i=2
For CH3OH
This has only 1 covalent bond.
Therefore i=1
MOLALITY:
(NH4)3PO4 = 0.75M
CaSO4= 1.0M
LiCl= 1.0M
CH3OH= 1.5M
FREEZING POINT DEPRESSION:
For (NH4)3PO4
∆T= 4×0.75×1.86=5.58°C
For CaSO4
∆T= 2×1.0×1.86=3.72°C
For LiCl
∆T = 2×1.0×1.86= 3.72°C
For CH3OH
∆T= 1×1.5×1.86=2.79°C
REMEMBER THE HIGHER THE FREEZING POINT DEPRESSION THE LOWER THE FREEZING POINT.
FREEZING POINT DEPRESSION IS THE CHANGE IN THE FREEZING POINT PROPORTIONAL TO THE AMOUNT OF SOLUTE ADDED THE THE SOLUTION.
THEREFORE THE ONE WITH THE LOWEST FREEZING POINT IS (NH4)3PO4
Answer:
ion exchange is the exchange of ions of the same charge between an insoluble solid and a solution in contact with it, used in water-softening and other purification and separation processes.
Explanation:
hope this helped !