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crimeas [40]
4 years ago
12

How to balance this by oxidation state change method? . KMnO4 + KCl + H2SO4 --> K2SO4 + MnSO4+Cl2+H2O

Chemistry
1 answer:
Juliette [100K]4 years ago
6 0
In this redox reaction, we must identify which is reduced and which is oxidized. Cl is oxidized from -1 to 0, Mn is reduced from +7 to +2. 

<span>MnO−4+Cl−→Mn2++Cl2</span>Balance the number of Cl first. <span>MnO−4+2Cl−→Mn2++C<span>l2
</span></span><span>MnO−4+10Cl−→2M<span>n2+</span>+5C<span>l2

</span></span>Balance the number of oxygen by adding <span>H2O</span> <span>2MnO−4+10Cl−→2M<span>n2+</span>+5Cl2+8H2O

</span>Balance the number of H by adding H+ <span>2MnO−4+10Cl−+16H+→2M<span>n2+</span>+5Cl2+8H2O

</span> Now, we know that there are 2 H+ in <span>H2SO4</span>, so, we can get <span>2MnO−4+10Cl−+8H2SO4→2M<span>n2+</span>+5Cl2+8H2O

</span> Put <span>S<span>O2−4</span></span> with <span>M<span>n2+</span></span> <span>2MnO−4+10Cl−+8H2SO4→2MnSO4+5Cl2+8H2O

</span> Add K in front of <span>MnO−4</span> and <span>Cl−</span> and balance it on the right <span>2KMnO4+10KCl+8H2SO4→12K++2MnSO4+5C<span>l<span>2 + 8H20

The final answer is </span></span></span>2KMn<span>O4</span><span>+10KCl+8</span><span>H2</span><span>S</span><span>O4</span><span>→6</span><span>K2</span><span>S</span><span>O4</span><span>+2MnS</span><span>O4</span><span>+5C</span><span>l2</span><span>+8</span><span>H2</span><span>O</span>
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