Answer:
The difference in the electronegativities of chlorine and boron is 3.0 - 2.0 = 1.0 ; the difference in between chlorine and carbon is 3.0 = 2.5 = 0.5 . Consequently, the B-Cl bond is more polar ; the chlorine atom asrries the partial negative charge because it has higher electronegativity .
Explanation:
hope it helps!
Answer:
Acceleration = (change in speed) / (time for the change)
Change in speed= (0 - 26 km/hr) = -26 km/hr
(-26 km/hr) x (1,000 m/km) x (1 hr / 3,600 sec) = -7.222 m/sec
Average acceleration = (-7.222 m/s) / (22 min x 60sec/min) = -0.00547 m/sec²
Average speed during the stopping maneuver =
(1/2) (start speed + end speed) = 13 km/hr = 3.6111 m/sec
Explanation:
Energy is distributed not just in translational KE, but also in rotation, vibration and also distributed in electronic energy levels (if input great enough, bond breaks).
All four forms of energy are quantised and the quanta ‘gap’ differences increases from trans. KE ==> electronic.
Entropy (S) and energy distribution: The energy is distributed amongst the energy levels in the particles to maximise their entropy.
Entropy is a measure of both the way the particles are arranged AND the ways the quanta of energy can be arranged.
We can apply ΔSθsys/surr/tot ideas to chemical changes to test feasibility of a reaction:
ΔSθtot = ΔSθsys + ΔSθsurr
ΔSθtot must be >=0 for a chemical change to be feasible.
For example: CaCO3(s) ==> CaO(s) + CO2(g)
ΔSθsys = ΣSθproducts – ΣSθreactants
ΔSθsys = SθCaO(s) + SθCO2(g) – SθCaCO3(s)
ΔSθsurr is –ΔHθ/T(K) and ΔH is very endothermic (very +ve),
Now ΔSθsys is approximately constant with temperature and at room temperature the ΔSθsurr term is too negative for ΔSθtot to be plus overall.
But, as the temperature is raised, the ΔSθsurr term becomes less negative and eventually at about 800oCΔSθtot becomes plus overall (and ΔGθ becomes negative), so the decomposition is now chemically, and 'commercially' feasible in a lime kiln.
CaCO3(s) ==> CaO(s) + CO2(g) ΔHθ = +179 kJ mol–1 (very endothermic)
This important industrial reaction for converting limestone (calcium carbonate) to lime (calcium oxide) has to be performed at high temperatures in a specially designed limekiln – which these days, basically consists of a huge rotating angled ceramic lined steel tube in which a mixture of limestone plus coal/coke/oil/gas? is fed in at one end and lime collected at the lower end. The mixture is ignited and excess air blasted through to burn the coal/coke and maintain a high operating temperature.
ΔSθsys = ΣSθproducts – ΣSθreactants
ΔSθsys = SθCaO(s) + SθCO2(g) – SθCaCO3(s) = (40.0) + (214.0) – (92.9) = +161.0 J mol–1 K–1
ΔSθsurr is –ΔHθ/T = –(179000/T)
ΔSθtot = ΔSθsys + ΔSθsurr
ΔSθtot = (+161) + (–179000/T) = 161 – 179000/T
If we then substitute various values of T (in Kelvin) you can calculate when the reaction becomes feasible.
For T = 298K (room temperature)
ΔSθtot = 161 – 179000/298 = –439.7 J mol–1 K–1, no good, negative entropy change
For T = 500K (fairly high temperature for an industrial process)
ΔSθtot = 161 – 179000/500 = –197.0, still no good
For T = 1200K (limekiln temperature)
ΔSθtot = 161 – 179000/1200 = +11.8 J mol–1 K–1, definitely feasible, overall positive entropy change
Now assuming ΔSθsys is approximately constant with temperature change and at room temperature the ΔSθsurr term is too negative for ΔSθtot to be plus overall. But, as the temperature is raised, the ΔSθsurr term becomes less negative and eventually at about 800–900oC ΔSθtot becomes plus overall, so the decomposition is now chemically, and 'commercially' feasible in a lime kiln.
You can approach the problem in another more efficient way by solving the total entropy expression for T at the point when the total entropy change is zero. At this point calcium carbonate, calcium oxide and carbon dioxide are at equilibrium.
ΔSθtot–equilib = 0 = 161 – 179000/T, 179000/T = 161, T = 179000/161 = 1112 K
This means that 1112 K is the minimum temperature to get an economic yield. Well at first sight anyway. In fact because the carbon dioxide is swept away in the flue gases so an equilibrium is never truly attained so limestone continues to decompose even at lower temperatures.
Explanation:
- Evaporation is defined as a process in which liquid state of water is changing into vapor state.
So, we need to break the bonds of liquid substance in order to convert it into vapor state. And, energy is absorbed for breaking of bonds which means that evaporation is an endothermic process.
Hence, the statement evaporation of water is an exothermic process is false.
- When a hydrocarbon reacts with oxygen and leads to the formation of carbon dioxide and water then this type of reaction is known as combustion reaction.
A combustion reaction will always release heat energy. Hence, combustion reaction is exothermic in nature.
- When energy is transferred as heat from the surroundings to the system then it means energy is being absorbed by the system. And, absorption of heat is an endothermic process for which
is positive.
- Whereas when energy is transferred from system to the surrounding then it means energy is released by the system which is an exothermic process.
Hence, for an exothermic process value of is negative.
Thus, we can conclude that statements which are true are as follows.
- A combustion reaction is exothermic.
- When energy is transferred as heat from the system to the surroundings, is negative.
- For an endothermic reaction Deta H is positive.
