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marta [7]
2 years ago
11

In the preparation of a certain alkyl halide, 10 g of sodium bromide (NaBr), 10 mL distilled water (H20), and 9 mL 3-methyl-1-bu

tanol (C5H120) were mixed in the round-bottomed flask and allowed to cool for 2 -3 minutes. Then while swirling the flask, 10 mL sulfuric acid (H2SO4) was slowly added to the flask and the mixture was refluxed and later distilled. The mass of the pure product obtained was 6.48 g. Sodium hydrogen carbonate (NaHCO3) was used to remove impurities. (Density of 3-methyl-1-butanol is 0.810 g/mL). The percentage yield will be?​
Chemistry
1 answer:
Novosadov [1.4K]2 years ago
7 0

Percentage yield shows the amount of reactants converted into products. The percentage yield of the reaction is 51.7%.

The equation of the reaction is sown in the image attached. The reaction is 1:1 as we can see.

Number of moles of NaBr = 10 g/103 g/mol = 0.097 moles

We can obtain the mass of 3-methyl-1-butanol from its density.

Mass = density × volume

Density of 3-methyl-1-butanol =  0.810 g/mL

Volume of  3-methyl-1-butanol = 9 mL

Mass of 3-methyl-1-butanol = 0.810 g/mL × 9 mL

Mass of 3-methyl-1-butanol = 7.29 g

Number of moles of 3-methyl-1-butanol =  mass/molar mass =  7.29 g/88 g/mol = 0.083 moles

Since the reaction is 1:1 then the limiting reagent is 3-methyl-1-butanol

Mass of product 1-bromo-3-methylbutane = number of moles × molar mass

Molar mass of 1-bromo-3-methylbutane = 151 g/mol

Mass of product 1-bromo-3-methylbutane = 0.083 moles × 151 g/mol

= 12.53 g

Recall that % yield = actual yield/theoretical yield × 100

Actual yield of product = 6.48 g

Theoretical yield = 12.53 g

% yield = 6.48 g/12.53 g × 100

% yield = 51.7%

Learn more: brainly.com/question/5325004

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An elemental analysis is performed in an unknown compound. It is found to contain 40.0 % mass in Carbon, 6.71% mass in Hydrogen,
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Answer: Molecular formula will be C_3H_6O_3

Explanation:

If percentage are given then we are taking total mass is 100 grams.

So, the mass of each element is equal to the percentage given.

Mass of C= 40 g

Mass of H = 6.71 g

Mass of O = 100 - (40+6.71 ) = 53.29 g

Step 1 : convert given masses into moles.

Moles of C =\frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{40g}{12g/mole}=3.33moles

Moles of H =\frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{6.71g}{1g/mole}=6.71moles

Moles of O =\frac{\text{ given mass of O}}{\text{ molar mass of O}}= \frac{53.29g}{16g/mole}=3.33moles

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C = \frac{3.33}{3.33}=1

For H =\frac{6.71}{3.33}=2

For O = \frac{3.33}{3.33}=1

The ratio of C: H: O= 1 : 2: 1

Hence the empirical formula is CH_2O

The empirical weight of CH_2O = 1(12)+2(1)+1(16)= 30g.

The molecular weight = 90.08 g/mole

Now we have to calculate the molecular formula:

n=\frac{\text{Molecular weight}}{\text{Equivalent weight}}=\frac{90.08}{30}=3

The molecular formula will be=3\times CH_2O=C_3H_6O_3

Molecular formula will be C_3H_6O_3

6 0
3 years ago
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