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Vilka [71]
3 years ago
7

Given the ion C2O4-2, what species would you expect to form with each of the following ions?

Chemistry
1 answer:
Ksivusya [100]3 years ago
6 0

Answer:

A. K₂C₂O₄          Potassium oxalate

B. CuC₂O₄          Copper oxalate

C. Bi₂(C₂O₄)₃         Bismuth (III) oxalate

D. Pb(C₂O₄)₂         Lead (IV) oxalate

E. (NH₄)₂C₂O₄       Ammonium oxalate

F. HC₂O₄⁻             Acid oxalate

Explanation:

C₂O₄⁻²  → oxalate anion

This is the conjugate base from the H₂C₂O₄ which is the oxalic acid. A weak dyprotic acid that can release 2 protons.

A. 2K⁺  +  C₂O₄⁻²  → K₂C₂O₄          Potassium oxalate

It can be formed by the neutralization of the acid with the base

H₂C₂O₄  + 2KOH  → K₂C₂O₄  +  2H₂O

B. Cu²⁺ +  C₂O₄⁻²   ⇄  CuC₂O₄  ↓

This is a precipitate.

C.  2Bi³⁺  +  3C₂O₄⁻²   ⇄  Bi₂(C₂O₄)₃  ↓

This is a precipitate.

D.  Pb⁴⁺ +  2C₂O₄⁻²   ⇄  Pb(C₂O₄)₂  ↓

This is a precipitate.

E. 2NH₄⁺  +  C₂O₄⁻²   ⇄  (NH₄)₂C₂O₄  ↓

This is a precipitate.

F. This is the conjugate strong base, for the weak acid

H⁺  +  C₂O₄⁻²   ⇄  HC₂O₄⁻

HC₂O₄⁻  + H₂O  ⇄  C₂O₄⁻²  +  H₃O⁺    Ka

HC₂O₄⁻  + H₂O  ⇄  H₂C₂O₄  +  OH⁻    Kb

HC₂O₄⁻  is an amphoteric compound

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0.574moles

Explanation:

Using the general gas equation;

PV = nRT

Where;

P = pressure (atm)

V = volume (Litres)

n = number of moles (mol)

R = gas law constant (0.0821 Latm/molK)

T = temperature (Kelvin)

According to the information provided in the question;

- Volume (V) = 12400mL = 12400/1000 = 12.4L

- Pressure (P) = 890mmHg = 890/760 = 1.17atm

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Hence, using PV = nRT

n = PV/RT

n = 1.17 × 12.4 ÷ 0.0821 × 308

n = 14.508 ÷ 25.287

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