Question

Now they feel it is best to have you identify an unknown gas based on its properties. Suppose 0.508 g of a gas occupies a volume of 0.175 L at a temperature of 25.0◦C is held at a pressure of 1.000 atm. What gas is this most likely?
Neon
Chlorine
Fluorine
Oxygen
Krypton

Answer 1

Answer: Option (b) is the correct answer.

Explanation:

The given data is as follows.

             mass = 0.508 g,               Volume = 0.175 L

             Temperature = (25 + 273) K = 298 K,       P = 1 atm

As per the ideal gas law, PV = nRT.

where,  n = no. of moles = $\frac{mass}{\text{molar mass}}$

Hence, putting all the given values into the ideal gas equation as follows.

               PV = $\frac{mass}{\text{molar mass}} \times RT$            

           1 atm \times 0.175 L = $\frac{0.508 g}{\text{molar mass}} \times 0.0821 L atm/ K mol \times 298 K$  

                            = 71.02 g

As the molar mass of a chlorine atom is 35.4 g/mol and it exists as a gas. So, molar mass of $Cl_{2}$ is 70.8 g/mol or 71 g/mol (approx).

Thus, we can conclude that the gas is most likely chlorine.