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The reaction described by H2(g)+I2(g)⟶2HI(g) has an experimentally determined rate law of rate=k[H2][I2] Some proposed mechanism

MatroZZZ [7]

Answer:

Mechanism A and B are consistent with observed rate law

Mechanism A is consistent with the observation of J. H. Sullivan

Explanation:

In a mechanism of a reaction, the rate is determinated by the slow step of the mechanism.

In the proposed mechanisms:

Mechanism A

(1) H2(g)+I2(g)→2HI(g)(one-step reaction)

Mechanism B

(1) I2(g)⇄2I(g)(fast, equilibrium)

(2) H2(g)+2I(g)→2HI(g) (slow)

Mechanism C

(1) I2(g) ⇄ 2I(g)(fast, equilibrium)

(2) I(g)+H2(g) ⇄ HI(g)+H(g) (slow)

(3) H(g)+I(g)→HI(g) (fast)

The rate laws are:

A: rate = k₁ [H2] [I2]

B: rate = k₂ [H2] [I]²

As:

K-1 [I]² = K1 [I2]:

rate = k' [H2] [I2]

Where K' = K1 * K2

C: rate = k₁ [H2] [I]

As:

K-1 [I]² = K1 [I2]:

rate = k' [H2] [I2]^1/2

Thus, just mechanism A and B are consistent with observed rate law

In the equilibrium of B, you can see the I-I bond is broken in a fast equilibrium (That means the rupture of the bond is not a determinating step in the reaction), but in mechanism A, the fast rupture of I-I bond could increase in a big way the rate of the reaction. Thus, just mechanism A is consistent with the observation of J. H. Sullivan

5 0

3 years ago

Now consider the reaction a+2b⇌c for which in the initial mixture qc=[c][a][b]2=387 is the reaction at equilibrium? if not, in w

Paul [167]

Solving this chemistry is a little bit hard because the question didn't give some important detailed.
So first, there are a couple problems with your question.
We will just need to know which direction will it proceed to reach equilibrium.
Your expression for Kc (and Qc ) for the reaction should be:
Kc = [C] / [A] [B]^2
You have not provided a value for Kc, so a value of Qc tells you absolutely nothing. Qc is only valuable in relation to a numerical value for Kc. If Qc = Kc, then the reaction is at equilibrium. If Q < K, the reaction will form more products to reach equilibrium, and if Q > Kc, the reaction will form more reactants.

5 0

3 years ago

What are the main method of combination?

Pepsi [2]

Explanation:

Each atom type contains the same number of protons. Chemical bonds link elements together to form more complex molecules called compounds. A compound consists of two or more types of elements held together by covalent or ionic bonds

7 0

2 years ago

Crime scene investigators keep a wide variety of compounds on hand to help with identifying unknown substances they find in the

almond37 [142]

The powder could be acetaminophen, analgesic having chemical formula $C_{17}H_{21}NO_{4}$

<h3>What is an empirical formula?</h3>

A chemical formula showing the simplest ratio of elements in a compound rather than the total number of atoms in the molecule.

We are given:

Percentage of C = 67.31 %

Percentage of H = 6.978 %

Percentage of N = 4.617 %

Percentage of O = 21.10 %

Let the mass of the compound be 100 g. So, the percentages given are taken as mass.

Mass of C = 67.31 g

Mass of H = 6.978 g

Mass of N = 4.617 g

Mass of O = 21.10 g

To formulate the empirical formula, we need to follow some steps:

Step 1: Converting the given masses into moles.

Moles of carbon = $\frac{mass}{molar \;mass}$

Moles of carbon = $\frac{67.31g}{12g/mole}$

=5.60 moles

Moles of hydrogen = $\frac{mass}{molar \;mass}$

Moles of hydrogen = $\frac{6.978 g}{1 g/mole}$

=6.978 moles

Moles of nitrogen = $\frac{mass}{molar \;mass}$

Moles of nitrogen = $\frac{4.617 g}{14 g/mole}$

=0.329 moles

Moles of oxygen = $\frac{mass}{molar \;mass}$

Moles of oxygen = $\frac{21.10 g}{16 g/mole}$

=1.31 moles

Step 2: Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 0.329 moles.

We get the ratio of C : H : N : O = 17 : 21 : 1 : 4

The empirical formula for the given compound is $C_{17}H_{21}NO_{4}$ .

Learn more about the empirical formula here:

brainly.com/question/14044066

#SPJ1

3 0

2 years ago

Which one of the following atoms has the largest radius? Ова Осо OCa

RUDIKE [14]

Answer:

Ba

Explanation:

The elements Calcium ( Ca ) and Cobalt ( Co ) , are both present in the same period , and across the period the atomic radius decreases from left to right , since , the atomic number increases , so the electrons increases , which in turns increases the effective nuclear charge , and hence the size decreases ,

Therefore ,

Calcium will have bigger atomic radii as compared to Cobalt .

Now,

The elements Barium ( Ba ) and Calcium ( Ca ) are , both are present in the same group , and down the group , atomic radii increases , since , as going down the group , the atomic number increase , so the shells increases , hence the size increases .

Therefore , the atom with the largest radii is Barium .

7 0

3 years ago