Substitution Reactions are those reactions in which one nucleophile replaces another nucleophile present on a substrate. These reactions can take place via two different mechanism i.e SN¹ or SN². In SN¹ substitution reactions the leaving group leaves first forming a carbocation and nucleophile attacks carbocation in the second step. While in SN² reactions the addition of Nucleophile and leaving of leaving group take place simultaneously.
Example:
OH⁻ + CH₃-Br → CH₃-OH + Br⁻
In above reaction,
OH⁻ = Incoming Nucleophile
CH₃-Br = Substrate
CH₃-OH = Product
Br⁻ = Leaving group
Organic reactions are typically slower than ionic reactions because in organic compounds the covalent bonds are first broken, this breaking of bonds is a slower step, while, in ionic compounds no bond breakage is required as it consists of ions, so only bond formation takes place which is a quicker and fast step.
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The reason we cannot breath liquid water is because the oxygen used to make the water is bound to two hydrogen atoms and we cannot breath the resulting liquid
<u>Answer:</u> The formation of given amount of oxygen gas results in the absorption of 713 kJ of heat.
<u>Explanation:</u>
To calculate the number of moles, we use the equation:
Given mass of oxygen gas = 83 g
Molar mass of oxygen gas = 32 g/mol
Putting values in above equation, we get:
For the given chemical equation:
<u>Sign convention of heat:</u>
When heat is absorbed, the sign of heat is taken to be positive and when heat is released, the sign of heat is taken to be negative.
By Stoichiometry of the reaction:
When 3 moles of oxygen gas is formed, the amount of heat absorbed is 824.2 kJ
So, when 2.594 moles of oxygen gas is formed, the amount of heat absorbed will be =
Hence, the formation of given amount of oxygen gas results in the absorption of 713 kJ of heat.