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GuDViN [60]
3 years ago
13

WILL GOVE BRAINLIEST NEED HELP ASAP!!!!

Chemistry
1 answer:
PolarNik [594]3 years ago
4 0

Answer:

Click on the image, click search for image on  g, then find the answer.

Explanation:

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3 years ago
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Pure chlorobenzene is contained in a flask attached to an open-end mercury manometer. When the flask contents are at 58.3°C, the
Elan Coil [88]

Answer:

 

The slope is 4661.4K

(B), the intercept is 18.156

The vapor pressure of chlorobenzene is 731.4mmHg

The percentage of chlorobenzene originally in the vapor that condenses is = 99.7%

Explanation:

Two sets of conditions (a and b) are observed for L1 and L2 at two different temperatures.

T_{a} = 58.3°C

L1_{a} = 747mmHg

L2_{a} = 52mmHg

T_{b} = 110°C

L1_{a} = 577mmHg

L2_{b} = 222mmHg

We need to convert the temperatures from Celsius to Kelvin (K)

T_{a} = 58.3°C + 273.2

T_{a} = 331.5k

T_{b} = 110°C + 273.2

T_{b} = 383.2k

We then calculate the vapor pressures of the chlorobenzene at each set of conditions by measuring the difference in the mercury levels.

P^{0} = P_{atm} - (P_1 -P_2)

The vapor pressure under the first set of conditions is:

P^{a} = 755mmHg - (747mmHg - 52mmHg)

P^{a} = 60mmHg

The vapor pressure under the second set of conditions is:

P^{b} = 755mmHg - (577mmHg = 222mmHg)

P^{b} = 400mmHg

First question say we should find ΔH(slope) and B(intercept) in the Clausius- Clapeyron equation:

Using the Formula :

In_p^{0} = \frac{- (delta) H}{RT} + B

where  (delta) H = ΔH

The slope of the In_p^{0} = \frac{T_1T_2 In (P_2/P_1)}{T_1-T_2}

Calculating the slope; we have:

\frac{- (delta) H}{R} = \frac{T_1T_2 In (P_2/P_1)}{T_1-T_2}

\frac{- (delta) H}{R} = \frac{331.5 * 383.2 * In (400/60)}{(331.5-383.2)}

\frac{- (delta) H}{R} = -4661.4k

\frac{ (delta) H}{R} = 4661.4k

The intercept can be derived from the Clausius-Clayperon Equation by making B the subject of the formula. To calculate the intercept using the first set of condition above; we have:

B = In_p_{1} + \frac{ (delta) H}{RT}

B = In 60 + \frac{4661.4}{331.5}

B = 18.156

Thus the Clausius-Clayperon equation for chlorobenzene can be expressed as:

In P = \frac{-4661.4k}{T} + 18.156

In question (b), the air saturated with chlorobenzeneis 130°C, converting he temperature  of 130°C to absolute units of kelvin(k) we have;

T = 130°C + 273.2

T = 403.2k

Calculating the vapor pressure using Clausius-Clapyeron equation: we have;

In_p_{0} = In_p_{0} = \frac{-4661.4}{403.2} + 18.156

In_p_{0} = 6.595

p_{0} = e^{6.595}

p_{0} = 731.mmHg

The vapor pressure of chlorobenzene is 731.4mmHg

The diagram of the flowchart with the seperate vapor and liquid stream can be found in the attached document below.

Afterwards, both the inlet and outlet conditions contain saturated liquid.

From the flowchart, the vapor pressure of chlorobenzene at the inlet and outlet temperatures are known:

P_1(130^{0}C) = 731.44mmHg

P_1(58.3^{0}C) = 60mmHg

To calculate the percentage of the chlorobenzene originally in the vapor pressure that condenses; we must first calculate the mole fractions of chlorobenzene for the vapor inlet and outlet using Raoult's Law:

y_1 = \frac{P^0 (T)}{P}

At inlet conditions, the mole fraction of chlorobenzene is:

y_1 = \frac{731.44}{101.3}*\frac{101.3}{760}

y_1 = \frac{0.962 mol cholorobenzene}{mol saturated air}

At outlet conditions , the mole fraction of chlorobenzene is:

y_2 = \frac{60}{101.3}*\frac{101.3}{760}

y_2 = \frac{0.0789 mol cholorobenzene}{mol saturated air}

Since there is no reaction, the total balance around the condensation is :

n_1 = n_2 + n_3

Let assume, that 100 moles of liquid chlorobenzene (CB) is condensed, therefore the equation becomes:

n_1 = n_2 + 100mol

The chlorobenzene balance using the mole fractions calculated above is :

\frac{0.962mol CB}{mol(air)} * n_1 mol(air) = \frac{0.0789molCB}{mol(air)}*n_2mol(air) + 100CB

substituting equation (1) into equation above; we have:

\frac{0.962mol CB}{mol(air)} * n_1 mol(air) = \frac{0.0789molCB}{mol(air)}*(n_2-100)mol(air) + 100CB

0.962_n_1 mol = 0.0789_n_1mol + 100mol

we can solve for n1, i.e ;

n1 = 104.3mol total air

Therefore the moles of chlorobenzene that will produce 100 moles of CB liquid is:

n_C_B = 104.3 (moles) air * \frac{0.962 mol (CB)}{mol air}

n_C_B = 100.34mol CB

Now, calculating the percentage of chlorobenzene that condenses: we have;

% CB Condensation =  \frac{100mol}{100.34mol}*100%

% CB Condensation = 99.7%

The percentage of chlorobenzene originally in the vapor that condenses is 99.7%

Download docx
4 0
4 years ago
Be sure to answer all parts. for each reaction, find the value of δso. report the value with the appropriate sign. (a) 3 no2(g)
Maurinko [17]

Answer:

Change in entropy for the reaction is

ΔS° = -268.13 J/K.mol

Explanation:

To calculate the change in entropy for the balanced reaction, we require the natural entropy of all the reactants and products in the reaction.

3 NO₂(g) + H₂O(l) → 2 HNO₃(l) + NO(g)

From Literature.

S°(NO₂) = 240.06 J/K.mol

S°(H₂O) = 69.91 J/K.mol

S°(HNO₃) = 155.60 J/K.mol

S°(NO) = 210.76 J/K.mol

These are the entropies of the reactants and products under standard conditions of 298.15 K and 1 atm.

Note that

ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)

Σ nᵢS°(for products) = [2 × S°(HNO₃)] + [1 × S°(NO)]

= (2 × 155.60) + (1 × 210.76) = 521.96 J/K.mol

Σ nᵢS°(for reactants) = [3 × S°(NO₂)] + [1 × S°(H₂O)]

= (3 × 240.06) + (1 × 69.91) =790.09 J/K.mol

ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)

ΔS° = 521.96 - 790.09 = -268.13 J/K.mol

Hope this Helps!!

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One problem with fuel-cell cars is that
allsm [11]

Answer: <u>Hydrogen.</u>

Explanation: <u>One problem with fuel-cell cars is that hydrogen gas is not readily available in pure form.</u> Fuel cell vehicles use hydrogen gas to power an electric motor. Unlike conventional vehicles which run on gasoline or diesel, fuel cell cars and trucks combine hydrogen and oxygen to produce electricity, which runs a motor. Hope this helps ^-^.

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3 years ago
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In which of these compounds are there twice as many oxygen atoms as hydrogen atoms?
Deffense [45]

Answer:

G - H2SO4

Explanation:

two hydrogen atoms and 4 oxygen atoms

8 0
3 years ago
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