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expeople1 [14]
3 years ago
11

Sodium benzoate, the sodium salt of benzoic acid, is used as a food preservative. A sample containing solid sodium benzoate mixe

d with sodium chloride is dissolved in 50.0 mL of .5 M HCl, giving an acidic solution (benzoic acid mixed with HCl ). This mixture is then titrated with .393 M NaOH. After the addition of 46.50 mL of the solution, the pH is found to be 8.2. At this point, the addition of one more drop ( .02 mL) of NaOH raises the pH to 9.3 . Calculate the mass of sodium benzoate (NaC6H5COO) in the original sample. (Hint: At the equivalence point, the total number of moles of acid [here HCl] equals the total number of moles of base [here, both NaOH and NaC6H5COO]
Chemistry
1 answer:
GalinKa [24]3 years ago
3 0

Answer:

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Explanation:

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Calculate the maximum volume (in mL) of 0.143 M HCl that each of the following antacid formulations would be expected to neutral
Nuetrik [128]

Answer:

a. The maximum volume of 0.143 M HCl required is 154.4 mL.

b. The maximum volume of 0.143 M HCl required is 135.7 mL.

Explanation:

a.

Al(OH)_3+3HCl\rightarrow AlCl_3+3H_2O

Mass of aluminum hydroxide = 350 mg =  0.350 g ( 1mg = 0.001 g)

Moles of aluminum hydroxide = \frac{0.350 g}{78 g/mol}=0.004487 mol

According to reaction ,3 moles of HCl neutralize 1 mole of aluminum hydroxide.Then 0.004487 mole of aluminum hydroxide will be neutralize by :

\frac{3}{1}\times 0.004487 mol=0.01346 mol of HCl.

Mg(OH)_2+2HCl\rightarrow MgCL_2+2H_2O

Mass of magnesium hydroxide = 250 mg =  0.250 g ( 1mg = 0.001 g)

Moles of magnesium hydroxide = \frac{0.250 g}{58 g/mol}=0.004310 mol

According to reaction ,2 moles of HCl neutralize 1 mole of magnesium hydroxide.Then 0.004310  mole of magnesium hydroxide will be neutralize by :

\frac{2}{1}\times 0.004310 mol=0.008621 mol of HCl.

Total moles of HCl required to neutralize both :

0.01346 mol + 0.008621 mol = 0.02208 mol

Molarity of the HCL solution = 0.143 M

Volume of the solution = V

Molarity=\frac{\text{Total moles of HCl}{\text{Volume in Liter}}

V=\frac{0.02208 mol}{0.143 M}=0.1544 L

1 L = 1000 mL

0.1544 L = 154.4 mL

The maximum volume of 0.143 M HCl required is 154.4 mL.

b.

CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2

Mass of calcium carbonate = 970mg =  0.970 g ( 1mg = 0.001 g)

Moles of calcium carbonate = \frac{0.970 g}{100 g/mol}=0.00970 mol

According to reaction ,2 moles of HCl neutralize 1 mole of calcium carbonate.Then 0.00970 mole of calcium carbonate will be neutralize by :

\frac{2}{1}\times 0.00970 mol=0.0194 mol of HCl.

Total moles of HCl required to neutralize calcium carbonate : 0.0194 mol

Molarity of the HCL solution = 0.143 M

Volume of the solution = V

Molarity=\frac{\text{Total moles of HCl}}{\text{Volume in Liter}}

V=\frac{0.0194 mol}{0.143 M}=0.1357 L

1 L = 1000 mL

0.1357 L = 135.7 mL

The maximum volume of 0.143 M HCl required is 135.7 mL.

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