Answer:
a) MZ₂
b) They have the same concentration
c) 4x10⁻⁴ mol/L
Explanation:
a) The solubility (S) is the concentration of the salt that will be dissociated and form the ions in the solution, the solubility product constant (Kps) is the multiplication of the concentration of the ions elevated at their coefficients. The concentration of the ions depends on the stoichiometry and will be equivalent to S.
The salts solubilization reactions and their Kps values are:
MA(s) ⇄ M⁺²(aq) + A⁻²(aq) Kps = S*S = S²
MZ₂(aq) ⇄ M⁺²(aq) + 2Z⁻(aq) Kps = S*S² = S³
Thus, the Kps of MZ₂ has a larger value.
b) A saturated solution is a solution that has the maximum amount of salt dissolved, so, the concentration dissolved is solubility. As we can notice from the reactions, the concentration of M⁺² is the same for both salts.
c) The equilibrium will be not modified because the salts have the same solubility. So, let's suppose that the volume of each one is 1 L, so the number of moles of the cation in each one is 4x10⁻⁴ mol. The total number of moles is 8x10⁻⁴ mol, and the concentration is:
8x10⁻⁴ mol/2 L = 4x10⁻⁴ mol/L.
To determine the fraction of carbon in morphine, we need to know the chemical formula of morphine. From my readings, the chemical formula would be <span>C17H19NO<span>3. We assume we have 1 g of this substance. Using the molar mass, we can calculate for the moles of morphine. Then, from the formula we relate the amount of carbon in every mole of morphine. Lastly, we multiply the molar mass of carbon to obtain the mass of carbon. We calculate as follows:
1 g </span></span> <span>C17H19NO<span>3 ( 1 mol / 285.34 g ) ( 17 mol C / 1 mol </span></span> <span>C17H19NO3</span>) ( 12.01 g C / 1 mol C) = 0.7155 g C
Fraction of carbon = 0.7155 g C / 1 g <span>C17H19NO<span>3 = 0.7155</span></span>
FeCl₂ + 2NH₄OH → Fe(OH)₂ + 2NH₄Cl
