In this kind of exercises, you should use the "ideal gas" rules: PV = nRT
P should be in Pascal:
445mmHg = 59328Pa
1225mmHg = 163319Pa
V should be in cubic meter:
16L = 0.016 m3
R =

= constant

=

==> P1 * V1 = P2 * V2
V2 =

=
V2 = 0.00581 m3 = 5.81 L
I believe that it is a chemical change.
NO, it should not be the process is still the same . the only factors about it that should change is the experiment itself.:)
Answer:
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