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Dennis_Churaev [7]
3 years ago
7

5. Calculate the time required to deposit 0.37g of Silver from a silverNitrate solution using a current of 2.5A( Charge of Ag in

AgNO3 is + 1)​
Chemistry
1 answer:
Monica [59]3 years ago
8 0

Time required : 132.2 s

<h3>Further explanation</h3>

Given

mass of Silver = 0.37 g

current = 2.5 A

Required

time do deposit

Solution

Faraday's Law :

\tt W=\dfrac{e.i.t}{96500}

e = ar/valence (valence Ag = 1)

i = current

t = time = s

\tt 0.37~g=\dfrac{108/1\times 2.5~A\times t }{96500}\\\\t=132.2~s

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he rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy . If the rate c
Leya [2.2K]

The question is incomplete, here is the complete question:

The rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy Ea = 71.0 kJ/mol . If the rate constant of this reaction is 6.7 M^(-1)*s^(-1) at 244.0 degrees Celsius, what will the rate constant be at 324.0 degrees Celsius?

<u>Answer:</u> The rate constant at 324°C is 61.29M^{-1}s^{-1}

<u>Explanation:</u>

To calculate rate constant at two different temperatures of the reaction, we use Arrhenius equation, which is:

\ln(\frac{K_{324^oC}}{K_{244^oC}})=\frac{E_a}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

where,

K_{244^oC} = equilibrium constant at 244°C = 6.7M^{-1}s^{-1}

K_{324^oC} = equilibrium constant at 324°C = ?

E_a = Activation energy = 71.0 kJ/mol = 71000 J/mol   (Conversion factor:  1 kJ = 1000 J)

R = Gas constant = 8.314 J/mol K

T_1 = initial temperature = 244^oC=[273+244]K=517K

T_2 = final temperature = 324^oC=[273+324]K=597K

Putting values in above equation, we get:

\ln(\frac{K_{324^oC}}{6.7})=\frac{71000J}{8.314J/mol.K}[\frac{1}{517}-\frac{1}{597}]\\\\K_{324^oC}=61.29M^{-1}s^{-1}

Hence, the rate constant at 324°C is 61.29M^{-1}s^{-1}

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4 years ago
Which elements are magnetic in the periodic table?
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METALS ARE MAGNETIC(and maybe metalloids)

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How do chemists express the rates of chemical reactions
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Read 2 more answers
How many grams of NaF should be added to 500 mL of a 0.100 M solution of HF to make a buffer with a pH of 3.2
Korolek [52]

Answer:

2.25g of NaF are needed to prepare the buffer of pH = 3.2

Explanation:

The mixture of a weak acid (HF) with its conjugate base (NaF), produce a buffer. To find the pH of a buffer we must use H-H equation:

pH = pKa + log [A-] / [HA]

<em>Where pH is the pH of the buffer that you want = 3.2, pKa is the pKa of HF = 3.17, and [] could be taken as the moles of A-, the conjugate base (NaF) and the weak acid, HA, (HF). </em>

The moles of HF are:

500mL = 0.500L * (0.100mol/L) = 0.0500 moles HF

Replacing:

3.2 = 3.17 + log [A-] / [0.0500moles]

0.03 = log [A-] / [0.0500moles]

1.017152 = [A-] / [0.0500moles]

[A-] = 0.0500mol * 1.017152

[A-] = 0.0536 moles NaF

The mass could be obtained using the molar mass of NaF (41.99g/mol):

0.0536 moles NaF * (41.99g/mol) =

<h3>2.25g of NaF are needed to prepare the buffer of pH = 3.2</h3>
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It is effected by diffusion (the power of smell and wind spread) but a solid is not.
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