Answer:
A is a physical change, no atoms are being lost its still in it original form
B is a chemical change, it is losing atoms and changing into a new substance
Explanation:
heh.......... sorry man............... but this was posted over 5 hours ago........ so nobody is gonna see it and you probably dont need the answer anymore..... so errrr..... imma justtttt..... take these points :D
Answer
Part A:
Given equation:

The above equation is an example of a double replacement reaction. A double replacement (or double displacement) reaction is a reaction in which the positive and negative ions of two ionic compounds exchange.
Note: The oxidation number of:
K = +1
I = -1
Ba = +2
S = -2
So, the complete chemical equation including phases of the given reaction is:

Part B:
Given equation:

Also, the equation is an example of a double replacement reaction.
Note: The oxidation number of:
K = +1
Cl = -1
Ca = +2
S = -2
The complete chemical equation including phases of the given reaction is:
The square brackets are used in case of complex compounds. This is known as coordination sphere. There is a metal in the coordination sphere and ligands attached to it. This complete set of metals and ligands inside the brackets is complex ion or molecule.
The ions outside this coordination sphere are counter ions of the complex.
It represents that if the complex compound is dissolved in water it will give a complex ion and the counter ion. The atoms in the bracket cannot break there bonds and will remain un-dissociated.
If there is no such bracket then it will represent simple or binary salt.
Nitrogen is represented in the highest percentage by volume in dry air.