to make a number undefined make the denominator equal to zero. so just make b-1=0 and a-1=0 so to make the polynomial f(x) undefined, b has to be 1 and a needs to be 1.
I'm going to be honest the question is a little confusing cause of the beginning, but if you're looking for which angles are actually congruent it's ∠GAC ≅ ∠HFD