Alcohol evaporates because of its vapor pressure and therefore, its molecule lying at the surface of alcohol (liquid-gas boundary) breaks its hydrogen bonding and tends to escape out of the alcohol solution. It should be noted that alcohol evaporates at a faster rate than water.
The enthalpy of vaporization of H2O is higher than the enthalpy of fusion of H2O, therefore vaporizing the same mass of H2O would require more heat/energy than melting the same mass of H2O.
