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Elodia [21]
3 years ago
5

One gram of alum, KAl(SO4)2.12H2O, contains 1.3 × 1021 Al atoms. How many oxygen atoms are contained in 1.0 g alum?

Chemistry
2 answers:
Roman55 [17]3 years ago
6 0

From the chemical formula, 1 formula unit of KAl (SO4)2.12H2O encompasses 1 atom of Al = 4 * 2 atoms of O in KAl (SO4)2 + 12 atoms of O in 12H2O which is equal to 20 atoms of O.

So, if you have 1.3 × 10^21 Al atoms, you have 20 * 1.3 × 10^21 O atoms will now be equal to 2.6 * 10^22 atoms of O.

scoundrel [369]3 years ago
5 0

<u>Answer:</u> The number of oxygen atoms in given amount of alum are 2.53\times 10^{22}

<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Given mass of alum = 1 g

Molar mass of alum = 477.3884 g/mol

Putting values in above equation, we get:

\text{Moles of alum}=\frac{1g}{477.3884g/mol}=0.0021mol

In 1 mole of KAl(SO_4)_2.12H_2O, 1 mole of aluminium atom, 20 moles of oxygen atoms, 1 mole of potassium atom, 2 moles of sulfur atom and 21 moles of hydrogen atoms are present.

According to the mole concept:

1 mole of a substance contains 6.022\times 10^{23} number of atoms.

So, 0.0021 moles of alum will contain 20\times 0.0021\times 6.022\times 10^{23}=2.53\times 10^{22} number of oxygen atoms.

Hence, the number of oxygen atoms in given amount of alum are 2.53\times 10^{22}

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Substance ΔG°f(kJ/mol) M3O4(s) −8.80 M(s) 0 O2(g) 0 Consider the decomposition of a metal oxide to its elements, where M represe
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Answer:

The equilibrium constant is  K =0.02867

The equilibrium pressure for oxygen gas is  P_{O_2} =  0.09367\  atm

Explanation:

  From the question we are told that

       The equation of the chemical reaction is

                    M_2 O_3 _{(s)} ----> 2M_{(s)} + \frac{3}{2} O_2_{(g)}

   The Gibbs free energy forM_3 O_4_{(s)} is  \Delta G^o_{1}  = -8.80 \ kJ/mol

  The Gibbs free energy forM{(s)} is  \Delta G^o_{2}  = 0 \ kJ/mol

    The Gibbs free energy forO_2{(s)} is  \Delta G^o_{3}  = 0 \ kJ/mol

The Gibbs free energy of the reaction is mathematically represented as

         \Delta G^o_{re} = \sum \Delta G^o _p - \sum G^o _r

         \Delta G^o_{re} = \sum \Delta G^o _1 - \sum( G^o _2 +G^o _3)

Substituting values

From the balanced equation

         \Delta G^o_{re} =[ (2 * 0) + (\frac{3}{2} * 0 )] - [1 * - 8.80]

        \Delta G^o_{re} = 8.80 kJ/mol =8800J/mol

The Gibbs free energy of the reaction can also be represented mathematically as

           \Delta G^o_{re} = -RTln K

Where R is the gas constant with a value of  R = 8.314 J/mol \cdot K

             T is the temperature with a given value  of  T = 298 K

             K is the equilibrium constant

Now equilibrium constant for a reaction that contain gas is usually expressed in term of the partial pressure of the reactant and products that a gaseous in state

The equilibrium constant for this chemical reaction  is mathematically represented as

                          K_p =[ P_{O_2}]^{\frac{3}{2} }

Where   [ P_{O_2}] is the equilibrium pressure of oxygen

         The p subscript shows that we are obtaining the equilibrium constant using the partial pressure of gas in the reaction

Now equilibrium constant the subject on the  second equation of the Gibbs free energy of the reaction

 

           K = e^{- \frac{\Delta G^o_{re}}{RT} }

Substituting values

           K= e^{\frac{8800}{8.314 * 298} }

            K =0.02867

Now substituting this into the equation above to obtain the equilibrium of oxygen

           0.02867 = [P_{O_2}]^{[\frac{3}{2} ]}

multiplying through by 1 ^{\frac{2}{3} }

        P_{O_2} =  [0.02867]^{\frac{2}{3} }

        P_{O_2} =  0.09367\  atm

       

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