C.) 45 AND 75............
It would not be plants, even though it has cell walls. They are not made of chitin. Plants are also not heterotrophic.
Fungi, however, decompose other matter, and have cell walls made of chitin. This would fit the description.
D.)The enzyme changes shape and no longer fits the substrate.
High temp causes enzymes to speed up the reaction but too much heat and the enzyme might denature, losing its shape.