Answer:
a. 750Hz, b. 4.0ppm, c. 600Hz
Explanation:
The Downfield Shift (Hz) is given by the formula
Downfield Shift (Hz) = Chemical Shift (ppm) x Spectrometer Frequency (Hz)
Using the above formula we can solve all three parts easily
a. fspec = 300 MHz, Chem. Shift = 2.5ppm, 1MHz = 10⁶ Hz, 1ppm (parts per million) = 10⁻⁶
Downfield Shift (Hz) = 2.5ppm x 300MHz x (1Hz/10⁶MHz) x (10⁻⁶/1ppm)
Downfield Shift = 750 Hz
The signal is at 750Hz Downfield from TMS
b. Downfield Shift = 1200 Hz, Chemical Shift = ?
Chemical Shift = Downfield shift/Spectrometer Frequency
Chemical Shift = (1200Hz/300MHz) x (1ppm/10⁻⁶) = 4.0 ppm
The signal comes at 4.0 ppm
c. Separation of 2ppm, Downfield Shift = ?
Downfield Shift (Hz) = 2(ppm) x 300 (MHz) x (1Hz/10⁶MHz) x (10⁻⁶/1ppm) = 600 Hz
The two peaks are separated by 600Hz
Answer:
pH = 5.47
Explanation:
The equilibrium that takes place is:
HIO ↔ H⁺ + IO⁻
Ka = ![\frac{[H+][IO-]}{[HIO]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BH%2B%5D%5BIO-%5D%7D%7B%5BHIO%5D%7D)
= 2.3 * 10⁻¹¹
At equilibrium:
<u>Replacing those values in the equation for Ka and solving for x:</u>
Then [H⁺]=3.39 * 10⁻⁶, thus pH = 5.47
Answer:
I think it's
there are the same number of molecules on each side of the equation, then a change of pressure makes no difference to the position of equilibrium
Answer:
Just show them their place.
Explanation:
hope this helps
