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3 years ago

Match each statement with one of these terms.

Chemistry

1 answer:

skelet666 [1.2K]3 years ago

8 0

Answer:

1 - e, 2 - k, 3 - a, 4 - i, 5 - b,

Explanation:

The ratio of the amount of analyte in the stationary phase to the amount in the mobile phase. --- Retention factor.

Time it takes after sample injection into the column for the analyte peak to appear as it exits the column. -- Retention time

The process of extracting a component that is adsorbed to a given material by use of an appropriate solvent system. -- Elution

Measure of chromatographic column efficiency. The greater its value, the more efficient the column. -- Theoretical plate number

Gas, liquid, or supercritical fluid used to transport the sample in chromatographic separations. -- Mobile phase

Immiscible and immobile, it is packed within a column or coated on a solid surface. -- Stationary phase

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Verdich [7]

Answer:

-100 kJ

Explanation:

We can solve this problem by applying the first law of thermodynamics, which states that:

$\Delta U = Q-W$

where:

$\Delta U$ is the change in internal energy of a system

Q is the heat absorbed/released by the system (it is positive if absorbed by the system, negative if released by the system)

W is the work done by the system (it is positive if done by the system, negative if done on the system)

For the system in this problem we have:

W = +147 kJ is the work done by the system

Q = +47 kJ is the heat absorbed by the system

So , its change in internal energy is:

$\Delta U = +47 - (+147) =-100 kJ$

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Answer: The theoretical yield of aspirin is 4.14 g

Explanation:

To calculate the moles :

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mass of acetic anhydride = $density\times volume =1.082g/ml\times 3.71ml=4.01g$

$\text{Moles of acetic anhydride}=\frac{4.01g}{102.04g/mol}=0.039moles$

$C_9H_6O_3+C_4H_6O_3\rightarrow C_9H_8O_4+C_2H_3O_2$

According to stoichiometry :

1 mole of salycylic acid require 1 mole of acetic anhydride

Thus 0.023 moles of salycylic acid require= $\frac{1}{1}\times 0.023=0.023moles$ of acetic anhydride

Thus salycylic acid is the limiting reagent as it limits the formation of product and acetic anhydride is the excess reagent.

As 1 mole of salycylic give = 1 mole of aspirin

Thus 0.023 moles of salycylic acid give = $\frac{1}{1}\times 0.023=0.023moles$ of aspirin

Mass of aspirin = $moles\times {\text {Molar mass}}=0.023moles\times 180.15g/mol=4.14g$

Thus theoretical yield of aspirin is 4.14 g

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