Answer:
The standard enthalpy of formation of NOCl(g) at 25 ºC is 105 kJ/mol
Explanation:
The ∆H (heat of reaction) of the combustion reaction is the heat that accompanies the entire reaction. For its calculation you must make the total sum of all the heats of the products and of the reagents affected by their stoichiometric coefficient (number of molecules of each compound that participates in the reaction) and finally subtract them:
Enthalpy of the reaction= ΔH = ∑Hproducts - ∑Hreactants
In this case, you have: 2 NOCl(g) → 2 NO(g) + Cl₂(g)
So, ΔH=
Knowing:
- ΔH= 75.5 kJ/mol
= 90.25 kJ/mol
= 0 (For the formation of one mole of a pure element the heat of formation is 0, in this caseyou have as a pure compound the chlorine Cl₂)
=?
Replacing:
75.5 kJ/mol=2* 90.25 kJ/mol + 0 - 
Solving
-
=75.5 kJ/mol - 2*90.25 kJ/mol
-
=-105 kJ/mol
=105 kJ/mol
<u><em>The standard enthalpy of formation of NOCl(g) at 25 ºC is 105 kJ/mol</em></u>
<u>Answer:</u> The equilibrium concentration of water is 0.597 M
<u>Explanation:</u>
Equilibrium constant in terms of concentration is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as 
For a general chemical reaction:

The expression for
is written as:
![K_{c}=\frac{[C]^c[D]^d}{[A]^a[B]^b}](https://tex.z-dn.net/?f=K_%7Bc%7D%3D%5Cfrac%7B%5BC%5D%5Ec%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%5BB%5D%5Eb%7D)
The concentration of pure solids and pure liquids are taken as 1 in the expression.
For the given chemical reaction:

The expression of
for above equation is:
![K_c=\frac{[H_2O]^2}{[H_2S]^2\times [O_2]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BH_2O%5D%5E2%7D%7B%5BH_2S%5D%5E2%5Ctimes%20%5BO_2%5D%7D)
We are given:
![[H_2S]_{eq}=0.671M](https://tex.z-dn.net/?f=%5BH_2S%5D_%7Beq%7D%3D0.671M)
![[O_2]_{eq}=0.587M](https://tex.z-dn.net/?f=%5BO_2%5D_%7Beq%7D%3D0.587M)

Putting values in above expression, we get:
![1.35=\frac{[H_2O]^2}{(0.671)^2\times 0.587}](https://tex.z-dn.net/?f=1.35%3D%5Cfrac%7B%5BH_2O%5D%5E2%7D%7B%280.671%29%5E2%5Ctimes%200.587%7D)
![[H_2O]=\sqrt{(1.35\times 0.671\times 0.671\times 0.587)}=0.597M](https://tex.z-dn.net/?f=%5BH_2O%5D%3D%5Csqrt%7B%281.35%5Ctimes%200.671%5Ctimes%200.671%5Ctimes%200.587%29%7D%3D0.597M)
Hence, the equilibrium concentration of water is 0.597 M
True because certain fabric will catch on fire