1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
ra1l [238]
3 years ago
11

The equilibrium constant for the reaction AgBr(s) Picture Ag+(aq) + Br− (aq) is the solubility product constant, Ksp = 7.7 × 10−

13 at 25°C. Calculate ΔG for the reaction when [Ag+] = 1.0 × 10−2 M and [Br-] = 1.0 × 10−3 M. Is the reaction spontaneous or nonspontaneous at these concentrations?
Chemistry
1 answer:
barxatty [35]3 years ago
5 0

Answer:

The reaction will be  non spontaneous at these concentrations.

Explanation:

AgBr(s)\rightarrow Ag^+(aq) + Br^- (aq)

Expression for an equilibrium constant K_c:

K_c=\frac{[Ag^+][Br^-]}{[AgCl]}=\frac{[Ag^+][Br^-]}{1}=[Ag^+][Br^-]

Solubility product of the reaction:

K_{sp}=[Ag^+][Br^-]=K_c=7.7\times 10^{-13}

Reaction between Gibb's free energy and equilibrium constant if given as:

\Delta G^o=-2.303\times R\times T\times \log K_c

\Delta G^o=-2.303\times R\times T\times \log K_{sp}

\Delta G^o=-2.303\times 8.314 J/K mol\times 298 K\times \log[7.7\times 10^{-13}]

\Delta G^o=69,117.84 J/mol=69.117 kJ/mol

Gibb's free energy when concentration [Ag^+] = 1.0\times 10^{-2} M and [Br^-] = 1.0\times 10^{-3} M

Reaction quotient of an equilibrium = Q

Q=[Ag^+][Br^-]=1.0\times 10^{-2} M\times 1.0\times 10^{-3} M=1.0\times 10^{-5}

\Delta G=\Delta G^o+(2.303\times R\times T\times \log Q)

\Delta G=69.117 kJ/mol+(2.303\times 8.314 Joule/mol K\times 298 K\times \log[1.0\times 10^{-5}])

\Delta G=40.588 kJ/mol

  • For reaction to spontaneous reaction:  \Delta G.
  • For reaction to non spontaneous reaction:  \Delta G>0.

Since ,the value of Gibbs free energy is greater than zero which means reaction will be non spontaneous at these concentrations

You might be interested in
Why do reactivity increases on moving from top to bottom in group 2 of modern periodic table?
Nikolay [14]

Answer:

that's because....

group 1 (e.g Na, K) those tend to lose one electron to gain noble gas electron configuration.

they can achieve that by just losing one electron from their outer shell.

as you go down the group 1, element gets bigger in size, which means there is more space between nucleus (which is in center of atom) and electron of outer shell. the more far away they are the less attraction force between them.

so its easier for potassuim to lose one electron than for lithuim.

so that means potassium will easily give up 1 electron to react with non metal or other element therefore it is more reactive than lithuim

but in case of non metal, the opposite happens but simple to understand.

as you go down the group 7 (halogen- Cl, Br, I) element will get bigger therefore force between nucleus and outer electron is getting smaller. they have to gain 1 electron in order to fill the outer shell (to gain noble gas electron configuration.)

as florine is more smaller in size than clorine it is more reactive because florine has more tendency to pull extra electron from metal or other element towards its side. so it easily gain 1 electron to react.

3 0
4 years ago
FOR NARUTO FANS ONLY
Andrei [34K]

Answer:

the last airbender is on Netfilx

Explanation:

go watch it

6 0
4 years ago
Read 2 more answers
Use your understanding of the ideal gas law to
PolarNik [594]

Answer:The ideal gas law is represented mathematically as: PV=nRT. P- pressure, V- volume, n-number of moles of gas, R- ideal gas constant, T- temperature.

Explanation:The ideal gas law is used as a prediction of the behavior of many gases, when subjected to different conditions.

he ideal gas law has so many limitations.

An increase in the pressure or volume, decreases the number of moles and temperature of the gas.

Empirical laws that led to generation of the ideal gas laws, considered two variables and keeping the others constant. This empirical laws include, Boyle's law, Charles's law, Gay Lusaac's law and Avogadro's law.

4 0
4 years ago
Read 2 more answers
The chemical mixture that composes our atmosphere is called
Sergio039 [100]
<span>The chemical mixture that composes our atmosphere is called Synopt.</span>
3 0
4 years ago
3. How many atoms are found in 5.20 g of magnesium (Mg)?
Ganezh [65]

Explanation:

In order to go from mass of magnesium to atoms of magnesium, we have to do two things:

   Convert mass of Mg to moles of Mg using the molar mass of Mg as a conversion factor

   Convert moles of Mg to atoms of Mg using Avogadro's number (6.02×1023) as a conversion factor

Step 1:

Before we start, I should note that the molar mass of Mg is 24.31gmol. We can go from mass to moles using dimensional analysis. The key to dimensional analysis is understanding that the units that you don't need any more cancel out, leaving the units that are desired:

48.60g

×1mol24.31g

=2.00mol

Step 2:

We'll use this relationship:

www.sprinklernewz.uswww.sprinklernewz.us

Using the moles of Mg that we just obtained, we can use Avogrado's number to perform dimensional analysis in order to cancel out units of mol to end up with atoms of Mg:

2.00mol

×6.02×1023atoms1mol

=1.204×1024atoms

Thus, 48.60g of Mg is equivalent to 1.204×1024atoms

Hope this helped :)

6 0
3 years ago
Other questions:
  • How many grams of solid barium sulfate form when 25.0 ml of 0.160 m barium chloride reacts with 68.0 ml of 0.055 m sodium sulfat
    9·1 answer
  • HelpUsing a 2-cm-thick piece of cardboard over a radiation source would be mosteffective for protecting against which type of ra
    5·2 answers
  • Does anyone know how to do common ion effect in chemistry?
    9·1 answer
  • SCIENCE QUESTION plz helpz
    8·1 answer
  • Convert 614 Cal to J. Only include the numerical value in your answer. Respond with the correct number of significant figures in
    12·1 answer
  • Assuming all volume measurements are made at the same temperature and pressure, what volume of hydrogen gas is needed to react c
    7·1 answer
  • True or false, physical properties are distinguished by the way something looks, taste, smell, and feels.
    12·2 answers
  • PLEASE HELP!!!!!!!!!!!!
    5·1 answer
  • Equilibrium describes the balance that results from a forward and reverse reaction proceeding at equal rates. Since reaction rat
    12·2 answers
  • Three examples of<br> solid and gas solution
    8·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!