1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
ra1l [238]
3 years ago
11

The equilibrium constant for the reaction AgBr(s) Picture Ag+(aq) + Br− (aq) is the solubility product constant, Ksp = 7.7 × 10−

13 at 25°C. Calculate ΔG for the reaction when [Ag+] = 1.0 × 10−2 M and [Br-] = 1.0 × 10−3 M. Is the reaction spontaneous or nonspontaneous at these concentrations?
Chemistry
1 answer:
barxatty [35]3 years ago
5 0

Answer:

The reaction will be  non spontaneous at these concentrations.

Explanation:

AgBr(s)\rightarrow Ag^+(aq) + Br^- (aq)

Expression for an equilibrium constant K_c:

K_c=\frac{[Ag^+][Br^-]}{[AgCl]}=\frac{[Ag^+][Br^-]}{1}=[Ag^+][Br^-]

Solubility product of the reaction:

K_{sp}=[Ag^+][Br^-]=K_c=7.7\times 10^{-13}

Reaction between Gibb's free energy and equilibrium constant if given as:

\Delta G^o=-2.303\times R\times T\times \log K_c

\Delta G^o=-2.303\times R\times T\times \log K_{sp}

\Delta G^o=-2.303\times 8.314 J/K mol\times 298 K\times \log[7.7\times 10^{-13}]

\Delta G^o=69,117.84 J/mol=69.117 kJ/mol

Gibb's free energy when concentration [Ag^+] = 1.0\times 10^{-2} M and [Br^-] = 1.0\times 10^{-3} M

Reaction quotient of an equilibrium = Q

Q=[Ag^+][Br^-]=1.0\times 10^{-2} M\times 1.0\times 10^{-3} M=1.0\times 10^{-5}

\Delta G=\Delta G^o+(2.303\times R\times T\times \log Q)

\Delta G=69.117 kJ/mol+(2.303\times 8.314 Joule/mol K\times 298 K\times \log[1.0\times 10^{-5}])

\Delta G=40.588 kJ/mol

  • For reaction to spontaneous reaction:  \Delta G.
  • For reaction to non spontaneous reaction:  \Delta G>0.

Since ,the value of Gibbs free energy is greater than zero which means reaction will be non spontaneous at these concentrations

You might be interested in
As the pressure on the surface of a liquid decreases, the temperature at which the liquid will boil
ankoles [38]

Answer: option (1) decreases.


Explanation:


May be you have experienced that: when you go to the beach, where the atmposhpere pressure is greater than the atmosphere pressure in places that are at higher altitudes, the water takes longer to boil. That is because the boiling temperature is greater, and you need more total heat (more time) to permit the liquid to reach that temperature.


The reason why that happens is because substances boil when the vapor pressure (the pressure of the particles of vapor over the liquid) equals the atmosphere pressure. So, when the atmposhere pressure increases, the temperature at which the vapor pressure reaches the atmosphere pressure also increases, and when the atmosphere pressure decreases, the temperature at which the vapor pressure reaches the atmosphere pressure decreases.



5 0
3 years ago
Read 2 more answers
Crime scene investigators keep a wide variety of compounds on hand to help with identifying unknown substances they find in the
almond37 [142]

The powder could be acetaminophen, analgesic  having chemical formula C_{17}H_{21}NO_{4}

<h3>What is an empirical formula?</h3>

A chemical formula showing the simplest ratio of elements in a compound rather than the total number of atoms in the molecule.

We are given:

Percentage of C = 67.31 %

Percentage of H = 6.978 %

Percentage of N = 4.617 %

Percentage of O = 21.10 %

Let the mass of the compound be 100 g. So, the percentages given are taken as mass.

Mass of C = 67.31 g

Mass of H = 6.978 g

Mass of N = 4.617 g

Mass of O = 21.10 g

To formulate the empirical formula, we need to follow some steps:

Step 1: Converting the given masses into moles.

Moles of carbon = \frac{mass}{molar \;mass}

Moles of carbon =\frac{67.31g}{12g/mole}

=5.60 moles

Moles of hydrogen = \frac{mass}{molar \;mass}

Moles of hydrogen = \frac{6.978 g}{1 g/mole}

=6.978 moles

Moles of nitrogen =\frac{mass}{molar \;mass}

Moles of nitrogen = \frac{4.617  g}{14 g/mole}

=0.329 moles

Moles of oxygen =\frac{mass}{molar \;mass}

Moles of oxygen =\frac{21.10 g}{16 g/mole}

=1.31 moles

Step 2: Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 0.329 moles.

We get the ratio of C : H : N : O = 17 : 21 : 1 : 4

The empirical formula for the given compound is C_{17}H_{21}NO_{4}.

Learn more about the empirical formula here:

brainly.com/question/14044066

#SPJ1

3 0
2 years ago
Write 2,469,100 in Engineering Notation with 3 significant figures.
Gala2k [10]

Answer: 2.47\times 10^{6}

Explanation:

Engineering notation : It is the representation of expressing the numbers that are too big or too small and are represented in the decimal form times 10 raise to the power.  It is similar to the scientific notation but in engineering notation, the powers of ten are always multiples of 3.

The engineering notation written in the form:

a\times 10^b

where,

a = the number which is greater than 0 and less than 999

b = an integer multiple of 3

Now converting the given value of 2,469,100 into engineering notation, we get 2.47\times 10^{6}

Hence, the correct answer is, 2.47\times 10^{6}

6 0
3 years ago
A buffer contains the weak acid HA and its conjugate base A-. the weak acid has a p Ka of 4.82 and the buffer has a pH of 4.25.
klasskru [66]
<span>I think the correct answer is A. A buffer is a substance that resists small change in the acidity of a solution when an acid or base is added to the solution. Usually, a buffer involves a weak acid or a weak alkali and one of its salt.</span>
3 0
2 years ago
Given the unbalanced equation: N2(g) + H2(g) → NH3(g)
mario62 [17]

Answer:

                   Option-4 (3:2) is the correct answer.

Explanation:

Following steps are taken to balance the given unbalanced chemical equation.

Step 1: Write the unbalanced chemical equation,

                         N₂ +  H₂ →  NH₃

Step 2: Balance Nitrogen Atoms;

There are 2 nitrogen atoms on left hand side and 1 nitrogen atoms on right hand site therefore, to balance them multiply NH₃ on right hand side by 2 i.e.

                         N₂ +  H₂ →  2 NH₃

Step 3: Balance Hydrogen Atoms;

Now, there are 2 hydrogen atoms on left hand side and 6 hydrogen atom on right hand site therefore, to balance them multiply H₂ on left hand side by 3 i.e.

                         N₂ +  3 H₂ →  2 NH₃

Now, the equation is balanced.

Step 4: Finding out mole ratios:

From balanced chemical equation it can be concluded that 3 moles of H₂ are involved in producing 2 moles of NH₃ hence, the mole ratio of consumption of H₂ to production of NH₃ is 3:2.

3 0
3 years ago
Other questions:
  • Classify each material as a polymer or a composite. plywood ,plastic, concrete ,fiber glass ,paper ,nylon
    6·2 answers
  • What is the conjugate acid in this reaction? HC2H3O2(aq)+H2O(l)⇌H3O++C2H3O−2(aq) View Available Hint(s) What is the conjugate ac
    13·1 answer
  • How many molecules are in 4.62 moles of nitric acid (HNO3)?
    14·1 answer
  • How many electrons do the following have?<br> Gold<br> Iron<br> Copper<br> Uranium
    13·1 answer
  • 1.0 mole of KCl(aq) is added to which solution to produce a precipitate?
    12·1 answer
  • One mole of silver has a mass of 107.9 grams. Approximately how many atoms of silver are present in one mole of silver?
    8·2 answers
  • Help me rn plz......​
    7·2 answers
  • Help with the 3rd question plslsls I’ll brainlist.
    9·1 answer
  • 6. An average Mastiff puppy weighs 2.72 kilograms. How many pounds is an average Mastiff puppy? (1lb = 453.6 g)
    15·1 answer
  • What is the name given to an ion that has lost electrons? someone help me please D:
    11·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!