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vivado [14]
2 years ago
9

How many moles of ammonia gas occupy 50 mL at at 700 kPa and 30.0 0C?

Chemistry
1 answer:
nalin [4]2 years ago
6 0

For the conversions

I will start with pressure
1atm=101.3kPa
x =700kPa
x=700kPa/101.3kPa
x=6.91atm

Temperature
273K+30.00C
303K

Volume
1L=1000ml
x =50ml
x=0.05L

PV=nRT
6.91*0.05=n*0.08206*303
0.3455=24.86418n
0.3455/24.86418=n
0.0138=n
number of moles = 0.0138moles

Note: 0.08206 is the gas constant in this case
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Answer:

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Answer:

[Ni²⁺] = 1.33 M

Explanation:

To do this, we need to use the Nernst equation which (in standard conditions of temperature)

E = E° - RT/nF lnQ

However R and F are constant, and the reaction is taking place in 25 °C so we can assume the nernst equation like this:

E = E° - 0.05916/n logQ

As the nickel is in the cathode, this means that this element is being reducted while Cadmium is being oxidized, therefore the REDOX reaction would be:

Cd(s) + Ni²⁺(aq) --------> Cd²⁺(aq) + Ni(s)

With this, Q:

Q = [Cd²⁺] / [Ni²⁺]

Now, we need to know the value of the standard reduction potentials, which can be calculated with the semi equations of reduction and oxidation:

Cd(s) ------------> Cd²⁺ + 2e⁻       E°₁ = 0.40 V

Ni²⁺ + 2e⁻ -------------> Ni(s)        E°₂ = -0.25 V

E° = E°₁ + E°₂

E° = 0.40 - 0.25 = 0.15 V

Now that we have all the data, we can solve for the [Ni²⁺]:

0.133 = 0.15 - 0.05916/2 log(5/[Ni²⁺])

0.133 - 0.15 = -0.05916/2 log(5/[Ni²⁺])

-0.017 = -0.02958 log(5/[Ni²⁺])

-0.017/-0.02958 = log(5/[Ni²⁺])

0.5747 = log(5/[Ni²⁺])

10^(0.5747) = 5/[Ni²⁺]

[Ni²⁺] = 5/3.7558

<h2>[Ni²⁺] = 1.33 M</h2>
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1) let's convert the grams of NH₃ to moles using the molar mass

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3) let's plug in the values into the molality formula

molality= mol/ Kg---> 0.881 mol/ 0.2500 kg= 3.52 m
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3 years ago
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