Pure liquids and solids at the equilibrium stage:
Pure solids and pure liquids are not included in expressions for the equilibrium constant of heterogeneous equilibria since their concentrations are constant across time. Therefore, including it in our equilibrium expression is not significant.
Equilibrium expression:
When a certain chemical reaction is in equilibrium, the rates of the forward and backward reactions are equal, which means that there is no net change in the concentrations of the reactants and products and that the reaction mixture's composition does not change.
The concentration of solid and liquid:
Solid or liquid concentration,
= No. of Moles/ Volume in L
= Mass/(Volume × molar mass)
= Density/ Molar mass
Pure solids and liquids have constant densities and molar masses at a constant temperature.
Because of this, they have constant molar concentrations, which means that they are not considered in the equilibrium constant for a heterogeneous reaction.
Learn more about the pure solids, liquids, and heterogenous mixture here,
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