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Akimi4 [234]
3 years ago
15

A gas is expanded from an initial volume of 1 L at 1 atm at 7 °C to a final volume of 5 L.

Chemistry
1 answer:
WITCHER [35]3 years ago
4 0

Answer:

0.40 atm

Explanation:

To answer this problem we can use the <em>combined gas law</em>:

  • T₂P₁V₁ = T₁P₂V₂

In this case:

  • T₂ = 287 °C ⇒ 287 + 273.16 = 560.16 K
  • P₁ = 1 atm
  • V₁ = 1 L
  • T₁ = 7 °C ⇒ 7 + 273.16 = 280.16 K
  • P₂ = ?
  • V₂ = 5 L

We <u>input the data</u>:

  • 560.16 K * 1 atm * 1 L = 280.16 K * P₂ * 5 L

And <u>solve for P₂</u>:

  • P₂ = 0.40 atm
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An equilibrium mixture contains 0.750 mol of each of the products (carbon dioxide and hydrogen gas) and 0.200 mol of each of the
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1.302  moles of carbon dioxide would have to be added

<h3>Further explanation</h3>

The equilibrium constant is the value of the product in the equilibrium state of the substance in the right (product) divided by the substance in the left (reactant) with the exponents of each reaction coefficient

The equilibrium constant is based on the concentration (Kc) in a reaction

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\large {\boxed {\bold {Kc ~ = ~ \frac {[C] ^ m [D] ^ n} {[A] ^ p [B] ^ q}}}}

While the equilibrium constant is based on partial pressure

\large {\boxed {\bold {Kp ~ = ~ \frac {[pC] ^ m [pD] ^ n} {[pA] ^ p [pB] ^ q}}}}

The value of Kp and Kc can be linked to the formula '

\large {\boxed {\bold {Kp ~ = ~ Kc. (R.T) ^ {\Delta n}}}}

R = gas constant = 0.0821 L.atm / mol.K

=n = number of product coefficients-number of reactant coefficients

An equilibrium mixture: 0.750 moles of CO2 and H2, and 0.200 moles of CO and H2O

  • We determine Kc (constant concentration)

\displaystyle Kc=\frac{0.75.0.75}{0.2.0.2}\\\\Kc=14.1

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Reaction :

                CO +H₂O ⇔ CO₂ + H₂

initially      0.2   0.2       0.75+x  0.75

reaction    0.1    0.1        0.1         0.1

product     0.3   0.3       0.65+x    0.65

\displaystyle Kc=\frac{(0.650+x)(0.65)}{0.3.0.3}\\\\14.1(0.09)=0.4225+0.65x\\\\1.269-0.4225=0.65x\\\\0.8465=0.65x\\\\x=1.302

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