1) how would you explain the plateaus in your heating and heating curves?

nordsb [41]

C. because i take college classes and I've did this before

4 0

3 years ago

The Ksp of AgI is 8.3× 10–17. You titrate 25.00 mL of 0.08160 M NaI with 0.05190 M AgNO3. Calculate pAg after the following volu

11111nata11111 [884]

Answer:

(a) 13.64; (b) 8.04; (c) 2.25

Explanation:

AgI(s) ⇌ Ag⁺(aq) + I⁻(aq)

$K_{\text{sp}} = {\text{[Ag$^{+}$][I$^{-}$]} = 8.3\times 10^{-17}$

(a) pAg at 35.10 mL

$\text{Moles of I$^{-}$} = \text{0.02500 L} \times \dfrac{\text{0.08160 mol}}{\text{1 L}} = 2.040 \times 10^{-3}\text{ mol/L }\\\text{Moles of Ag$^{+}$} = \text{0.03510 L} \times \dfrac{\text{0.05190 mol}}{\text{1 L}} = 1.822 \times 10^{-3}\text{ mol/L}$

AgI(s) ⇌ Ag⁺(aq) + I⁻(aq)

I/mol: 1.822 × 10⁻³ 2.040 × 10⁻³

C/mol: -1.822 × 10⁻³ -1.822 × 10⁻³

E/mol: 0 0.218 × 10⁻³

We have a saturated solution of AgI containing 0.218 × 10⁻³ mol of excess I⁻.

V = 25.00 mL + 35.10 mL = 60.10 mL

$\text{[I$^{-}$]} = \dfrac{0.218 \times 10^{-3}\text{ mol}}{\text{0.0610 L}} = 3.57 \times 10^{-3}\text{ mol/L}\\$

AgI(s) ⇌ Ag⁺(aq) + I⁻(aq)

E/mol·L⁻¹: s 3.57 × 10⁻³ + s

$K_{\text{sp}} = s(3.57 \times 10^{-3} + s) = 8.3\times 10^{-17}\\$

Check for negligibility:

$\dfrac{3.57 \times 10^{-3}}{8.3\times 10^{-17}} = 4.3 \times 10^{13} > 400\\\\\therefore s \ll 3.63 \times 10^{-3}\\K_{\text{sp}} = s\times 3.63 \times 10^{-3}= 8.3\times 10^{-17}\\\\s = \text{[Ag$^{+}$]} = \dfrac{8.3\times 10^{-17}}{3.63 \times 10^{-3}} =2.29 \times 10^{-14}\\\\\text{pAg} = -\log \left (2.29\times 10^{-14} \right) = \mathbf{13.64}$

(b) At equilibrium

AgI(s) ⇌ Ag⁺(aq) + I⁻(aq)

E/mol·L⁻¹: s s

$K_{\text{sp}} = s\times s = s^{2} = 8.3\times 10^{-17}\\s = \sqrt{8.3\times 10^{-17}} = 9.11 \times 10^{-9}\\\text{pAg} = -\log \left (9.11 \times 10^{-9} \right) = \mathbf{8.04}$

(c) At 47.10 mL

$\text{Moles of Ag$^{+}$} = \text{0.04710 L} \times \dfrac{\text{0.05190 mol}}{\text{1 L}} = 2.444 \times 10^{-3}\text{ mol}$

AgI(s) ⇌ Ag⁺(aq) + I⁻(aq)

I/mol: 2.444 × 10⁻³ 2.040 × 10⁻³

C/mol: -2.040 × 10⁻³ -2.040 × 10⁻³

E/mol: 0.404 × 10⁻³ 0

V = 25.00 mL + 47.10 mL = 72.10 mL

$\text{[Ag$^{+}$]} = \dfrac{0.404 \times 10^{-3}\text{ mol}}{\text{0.0721 L}} = 5.61 \times 10^{-3}\text{ mol/L}\\\text{pAg} = -\log(5.61 \times 10^{-3}) = \mathbf{2.25}$

6 0

4 years ago

How many liters of water can be made from 55.0 grams of oxygen gas and an excess of

BartSMP [9]

The answer is 8.2 liters

7 0

3 years ago

1. 4 Fe + 302 → 2 Fe,03

klasskru [66]

Answer:

1. 5.093 moles

2. 0.33 (rounded) moles

Explanation:

working out in image

4 0

3 years ago

Suppose you are performing a titration. At the beginning of the titration, you read the titrant volume as 2.51 mL. After running

antoniya [11.8K]

The volume of titrant required for the titration would be 27.44 mL

From the illustration, the initial titrant volume was 2.51 mL. This figure represents the initial reading on the burette.

In the same vein, the final volume of the titrant was 29.95 mL. This figure represents the final reading on the burette.

In order to get the volume of titrant used:

Volume of titrant used = final volume - initial volume

= 29.95 - 2.51

= 27.44 mL

More on the volume of titrant used in titrations can be found here: brainly.com/question/4250180

3 0

2 years ago