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vladimir2022 [97]
3 years ago
12

Write balanced net ionic equations and the corresponding equilibrium equations for the stepwise dissociation of the triprotic ac

id H3PO4.
Chemistry
1 answer:
Elza [17]3 years ago
3 0

Answer:

H_3PO_4(aq)+H_2O(l)\rightleftharpoons H_3O^+(aq)+H_2PO_4^{-}(aq); \ Ka_1

H_2PO_4^{-}(aq)+H_2O(l)\rightleftharpoons H_3O^+(aq)+HPO_4^{-2}(aq); \ Ka_2

HPO_4^{-2}(aq)+H_2O(l)\rightleftharpoons H_3O^+(aq)+PO_4^{-3}(aq); \ Ka_3

Explanation:

Hello!

In this case, since the phosphoric acid is a triprotic acid, we infer it has three stepwise ionization reactions in which one hydrogen ion is released at each step, considering they are undergone due to the presence of water, thus, we proceed as follows:

H_3PO_4(aq)+H_2O(l)\rightleftharpoons H_3O^+(aq)+H_2PO_4^{-}(aq); \ Ka_1

H_2PO_4^{-}(aq)+H_2O(l)\rightleftharpoons H_3O^+(aq)+HPO_4^{-2}(aq); \ Ka_2

HPO_4^{-2}(aq)+H_2O(l)\rightleftharpoons H_3O^+(aq)+PO_4^{-3}(aq); \ Ka_3

Moreover, notice each step has a different acid dissociation constant, which are quantified in the following order:

Ka1 > Ka2 > Ka3

Best regards!

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