Question

Using your data above, draw conclusions about the d-splitting for each ligand (H2O, en, phen). Order the complexes from least to greatest d-splitting, and discuss the reason for your ordering.

Answer 1

Answer:

H2O<en<phen

Explanation:

The degree of d- splitting is observed from the intensity of colour. The order of d splitting from least to greatest is H2O<en<phen. Phen shows the greatest d-splitting. The degree of splitting of d- orbitals by ligands depends on their relative positions in the spectrochemical series. The spectrochemical series is an experimentally determined series. The series separates the ligands into strong field and weak field ligands. Strong field ligands are found towards the end of the series. Strong field ligands such as en and phen can participate in metal to ligand or ligand to metal pi-bonding. Hence they cause more d-splitting. Ethylendiamine and phenanthroline occur towards the end of the spectrochemical series hence the higher order of d-splitting.