No. Since there will be more of a fine, there will be more tax to take away. If the discount is taken first, then there will be less money to calculate the tax from. So tax before the discount would be worse, because it would cost more
It would be 52 quarts of coffee because there are 32 fluid ounces in a quart by the U.S. standard. I hope this helps, if you need more help ask, and have a nice day! :)