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stich3 [128]
3 years ago
15

Need help asap - There is an error in the rate-determining step of the following proposed mechanism.

Chemistry
1 answer:
sdas [7]3 years ago
5 0

Answer:

CH4(g) + Cl2(g) → CH3(g) + HCl(g) and the rate rule is k1 = [CH4][Cl2]

Explanation:

Firstly, we must remember that the substitution reaction between halogens and alkanes to yield halogenoalkanes does not proceed by ionic mechanism rather it proceeds by free radical mechanism.

Now, if we look at the rate determining step as shown in the question, the elementary reaction equation of that step is not balanced.

Hence, the correct elementary reaction equation for the rate determining step and the rate law is; CH4(g) + Cl2(g) → CH3(g) + HCl(g) and the rate rule is k1 = [CH4][Cl2]

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Apply scientific knowledge and understanding to determine how many grams of carbon dioxide are produced from the combustion of 2
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Answer:

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Explanation:

To find the amount of carbon dioxide produced, you need to (1) convert grams C₃H₈ to moles C₃H₈ (via molar mass from periodic table), then (2) convert moles C₃H₈ to moles CO₂ (via mole-to-mole ratio via reaction coefficients), and then (3) convert moles CO₂ to grams CO₂ (via molar mass from periodic table). It is important to arrange the ratios/conversions in a way that allows for the cancellation of units. The desired unit should be in the numerator. The final answer should have 3 significant figures because the given value (250. grams) has 3 sig figs.

Molar Mass (C₃H₈): 3(12.01 g/mol) + 8(1.008 g/mol)

Molar Mass (C₃H₈): 44.094 g/mol

1 C₃H₈ + 5 O₂ ---> 3 CO₂ + 4 H₂O

Molar Mass (CO₂): 12.01 g/mol + 2(16.00 g/mol)

Molar Mass (CO₂): 44.01 g/mol

250. g C₃H₈         1 mole C₃H₈           3 moles CO₂              44.01 g
------------------  x  ----------------------  x  ----------------------  x  --------------------  =
                               44.094 g              1 mole C₃H₈            1 mole CO₂

= 749 grams CO₂

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