It’s lower, hope this helps with your issue and helps solve your problem, no problem
Answer:
Part a: <em>Units of k is </em>
<em> where reaction is first order in A and second order in B</em>
Part b: <em>Units of k is </em>
<em> where reaction is first order in A and second order overall.</em>
Part c: <em>Units of k is </em>
<em> where reaction is independent of the concentration of A and second order overall.</em>
Part d: <em>Units of k is </em>
<em> where reaction reaction is second order in both A and B.</em>
Explanation:
As the reaction is given as

where as the rate is given as
![r=k[A]^x[B]^y](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5Ex%5BB%5D%5Ey)
where x is the order wrt A and y is the order wrt B.
Part a:
x=1 and y=2 now the reaction rate equation is given as
![r=k[A]^1[B]^2](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5E1%5BB%5D%5E2)
Now the units are given as
![r=k[A]^1[B]^2\\M/s =k[M]^1[M]^2\\M/s =k[M]^{1+2}\\M/s =k[M]^{3}\\M^{1-3}/s =k\\M^{-2}s^{-1} =k](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5E1%5BB%5D%5E2%5C%5CM%2Fs%20%3Dk%5BM%5D%5E1%5BM%5D%5E2%5C%5CM%2Fs%20%3Dk%5BM%5D%5E%7B1%2B2%7D%5C%5CM%2Fs%20%3Dk%5BM%5D%5E%7B3%7D%5C%5CM%5E%7B1-3%7D%2Fs%20%3Dk%5C%5CM%5E%7B-2%7Ds%5E%7B-1%7D%20%3Dk)
The units of k is 
Part b:
x=1 and o=2
x+y=o
1+y=2
y=2-1
y=1
Now the reaction rate equation is given as
![r=k[A]^1[B]^1](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5E1%5BB%5D%5E1)
Now the units are given as
![r=k[A]^1[B]^1\\M/s =k[M]^1[M]^1\\M/s =k[M]^{1+1}\\M/s =k[M]^{2}\\M^{1-2}/s =k\\M^{-1}s^{-1} =k](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5E1%5BB%5D%5E1%5C%5CM%2Fs%20%3Dk%5BM%5D%5E1%5BM%5D%5E1%5C%5CM%2Fs%20%3Dk%5BM%5D%5E%7B1%2B1%7D%5C%5CM%2Fs%20%3Dk%5BM%5D%5E%7B2%7D%5C%5CM%5E%7B1-2%7D%2Fs%20%3Dk%5C%5CM%5E%7B-1%7Ds%5E%7B-1%7D%20%3Dk)
The units of k is 
Part c:
x=0 and o=2
x+y=o
0+y=2
y=2
y=2
Now the reaction rate equation is given as
![r=k[A]^0[B]^2](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5E0%5BB%5D%5E2)
Now the units are given as
![r=k[B]^2\\M/s =k[M]^2\\M/s =k[M]^{2}\\M^{1-2}/s =k\\M^{-1}s^{-1} =k](https://tex.z-dn.net/?f=r%3Dk%5BB%5D%5E2%5C%5CM%2Fs%20%3Dk%5BM%5D%5E2%5C%5CM%2Fs%20%3Dk%5BM%5D%5E%7B2%7D%5C%5CM%5E%7B1-2%7D%2Fs%20%3Dk%5C%5CM%5E%7B-1%7Ds%5E%7B-1%7D%20%3Dk)
The units of k is 
Part d:
x=2 and y=2
Now the reaction rate equation is given as
![r=k[A]^2[B]^2](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5E2%5BB%5D%5E2)
Now the units are given as
![r=k[A]^2[B]^2\\M/s =k[M]^2[M]^2\\M/s =k[M]^{2+2}\\M/s =k[M]^{4}\\M^{1-4}/s =k\\M^{-3}s^{-1} =k](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5E2%5BB%5D%5E2%5C%5CM%2Fs%20%3Dk%5BM%5D%5E2%5BM%5D%5E2%5C%5CM%2Fs%20%3Dk%5BM%5D%5E%7B2%2B2%7D%5C%5CM%2Fs%20%3Dk%5BM%5D%5E%7B4%7D%5C%5CM%5E%7B1-4%7D%2Fs%20%3Dk%5C%5CM%5E%7B-3%7Ds%5E%7B-1%7D%20%3Dk)
The units of k is 
Total in pot=28 L
400 mL in each bowl
16 bowls filled
1000mL=1L
16 bowls(400mL/1 bowl)=6400mL
6400mL(1L/1000mL)=6.4L
28L-6.4L=21.6 L
<span>Since these molecules are all non-polar, the only intermolecular force of attraction will be London dispersion forces. Since these increase by the size of the molecule, the boiling points will decrease in the same order:
Parafin > Heptadecane > hexane > 2,2-dimethylbutane > propane
For these two, hexane > 2,2-dimethylbutane, dispersion forces are greater in a molecule which is longer and unbranched compared to one which is branched and more compact.</span>
Answer:
Celsius +273.15
Explanation:
The two scales have the same size degree, but Kelvin is an absolute scale based on absolute zero while 0° in Celsius is based on the melting point of water. So, in order to convert from Celsius degrees to Kelvin we only need to add 273.15 to the given temperature:
K= °C + 273.15